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Alkali Wiki2Web Clarity Challenge

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Study Guide: Alkali: Chemical Principles, History, and Environmental Contexts

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Alkali: Chemical Principles, History, and Environmental Contexts Study Guide

Alkali: Definitions and Terminology

An alkali is fundamentally defined in chemistry as a basic salt of an alkali metal or an alkaline earth metal, or more broadly as any base that dissolves in water.

Answer: True

Explanation: The definition of an alkali encompasses basic salts of alkali or alkaline earth metals, and more broadly, any water-soluble base.

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The word 'alkali' originates from a Greek term meaning 'strong base'.

Answer: False

Explanation: The term 'alkali' is derived from the Arabic 'al qaly', meaning 'the calcined ashes', referring to its historical source from plant ashes, not a Greek term for 'strong base'.

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Chemists often use 'base' and 'alkali' interchangeably without any specific differentiation.

Answer: False

Explanation: Chemists differentiate between 'base' and 'alkali', with alkalis being a specific subset of bases, often defined by solubility or metal composition, even if the terms are used interchangeably in common parlance.

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The adjective 'alkalescent' is less frequently used than 'alkaline' as a synonym for basic, especially for water-soluble bases.

Answer: True

Explanation: The text states that 'alkalescent' is indeed less frequently used than 'alkaline' as a synonym for basic, particularly for water-soluble bases.

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The broad use of 'alkaline' as a synonym for 'basic' is because alkalis were the first bases known to conform to the Arrhenius definition.

Answer: True

Explanation: The widespread use of 'alkaline' as a synonym for 'basic' is attributed to alkalis being the initial bases identified that aligned with the Arrhenius definition.

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According to the source, what is one fundamental definition of an alkali in chemistry?

Answer: A basic salt of an alkali metal or an alkaline earth metal.

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From which language does the word 'alkali' originate?

Answer: Arabic

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How do chemists commonly differentiate 'alkali' from 'base'?

Answer: Alkalis are a specific subset of bases, often defined by solubility or metal composition.

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What does the Arabic term 'al qaly' or 'alkali' translate to?

Answer: The calcined ashes

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What is the broader definition of an alkali in relation to bases?

Answer: Any base that dissolves in water.

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Historical Production and Early Uses

Potash, an early alkaline substance, was primarily composed of sodium carbonate.

Answer: False

Explanation: Potash was primarily composed of potassium carbonate, not sodium carbonate.

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Caustic potash was traditionally used with animal fats to produce hard soaps through a process called saponification.

Answer: False

Explanation: Caustic potash was traditionally used to produce soft soaps, not hard soaps, through saponification.

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The chemical symbol for potassium, 'K', is derived from its German name 'Kalium'.

Answer: True

Explanation: The chemical symbol 'K' for potassium indeed originates from its German name 'Kalium', which itself is derived from 'alkali'.

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Slaked lime is chemically known as calcium carbonate.

Answer: False

Explanation: Slaked lime is chemically known as calcium hydroxide, not calcium carbonate.

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Potassium was first derived from caustic soda.

Answer: False

Explanation: Potassium was first derived from caustic potash, not caustic soda.

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The process of saponification converts fats into soap and is a relatively recent chemical discovery.

Answer: False

Explanation: Saponification, the process of converting fats into soap, has been known since antiquity, making it a very old chemical process, not a recent discovery.

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What was potash, an early alkaline substance, primarily composed of?

Answer: Potassium carbonate

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What was the traditional use of caustic potash?

Answer: To produce soft soaps with animal fats.

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What is the origin of potassium's chemical symbol 'K'?

Answer: Its German name 'Kalium'.

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How was caustic potash produced from potash?

Answer: By heating potash with calcium hydroxide.

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Chemical Properties and Indicators

All Arrhenius bases are considered alkalis.

Answer: False

Explanation: While all alkalis are Arrhenius bases, not all Arrhenius bases are alkalis. For example, ammonia is an Arrhenius base but not typically classified as an alkali.

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Moderately concentrated alkaline aqueous solutions typically have a pH of 10 or greater.

Answer: True

Explanation: Moderately concentrated alkaline solutions are indeed characterized by a pH value of 10 or higher.

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Phenolphthalein turns blue in the presence of a moderately concentrated alkaline solution.

Answer: False

Explanation: Phenolphthalein turns pink, not blue, in the presence of a moderately concentrated alkaline solution.

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Concentrated alkaline solutions are caustic and can cause chemical burns.

Answer: True

Explanation: Concentrated alkaline solutions are indeed caustic and can cause chemical burns due to their corrosive nature.

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The slippery sensation when touching alkaline solutions is due to their reaction with skin proteins.

Answer: False

Explanation: The slippery sensation is caused by the saponification of fatty substances on the skin's surface, not a reaction with skin proteins.

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All alkalis are water-soluble without exception.

Answer: False

Explanation: While most alkalis are water-soluble, there are exceptions, such as barium carbonate, which only dissolves when reacting with an acidic aqueous solution.

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A solution of a soluble base will have a pH less than 7.0, indicating its acidic nature.

Answer: False

Explanation: A solution of a soluble base (an alkali) will have a pH greater than 7.0, indicating its basic nature.

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When alkalis dissolve in water, they form hydrogen ions (H⁺).

Answer: False

Explanation: When alkalis dissolve in water, they form hydroxide ions (OH⁻), which is characteristic of Arrhenius bases, not hydrogen ions.

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The pH of an alkaline solution is always exactly 7.0.

Answer: False

Explanation: An alkaline solution has a pH greater than 7.0; a pH of exactly 7.0 indicates a neutral solution.

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What happens when alkalis are dissolved in water, making them Arrhenius bases?

Answer: They form hydroxide ions (OH⁻).

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Which of the following is a common property of moderately concentrated alkaline aqueous solutions?

Answer: They feel slippery or soapy to the touch.

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What is the typical pH range for moderately concentrated alkaline solutions?

Answer: 10 or greater

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What visual change does phenolphthalein undergo in an alkaline solution?

Answer: Turns colorless to pink

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Why do concentrated alkaline solutions cause chemical burns?

Answer: They are caustic substances.

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What causes the slippery or soapy sensation when touching alkaline solutions?

Answer: The saponification of fatty substances on the skin.

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Which of the following alkalis is mentioned as an exception to general water solubility, dissolving only when reacting with an acidic aqueous solution?

Answer: Barium carbonate

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What is the significance of a solution having a pH greater than 7.0 in relation to alkalis?

Answer: It indicates the solution is basic.

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Specific Alkali Compounds and Common Names

Lye is a generic term specifically for sodium hydroxide.

Answer: False

Explanation: Lye is a generic term that can refer to sodium hydroxide, potassium hydroxide, or a mixture of both.

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Magnesium hydroxide is considered a typical alkali due to its high solubility in water.

Answer: False

Explanation: Magnesium hydroxide is considered an atypical alkali precisely because of its low solubility in water, despite its dissolved portion being a strong base.

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Sodium hydroxide is commonly known as 'caustic potash'.

Answer: False

Explanation: Sodium hydroxide is commonly known as 'caustic soda', whereas 'caustic potash' refers to potassium hydroxide.

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The saturated solution of calcium hydroxide is known as 'limewater'.

Answer: True

Explanation: The saturated solution of calcium hydroxide is indeed referred to as 'limewater'.

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The chemical formula for potassium hydroxide is NaOH.

Answer: False

Explanation: The chemical formula for potassium hydroxide is KOH, while NaOH is the formula for sodium hydroxide.

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What is the common name for sodium hydroxide (NaOH)?

Answer: Caustic soda

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Why is magnesium hydroxide considered an atypical alkali?

Answer: It has low solubility in water.

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What is the common name for potassium hydroxide (KOH)?

Answer: Caustic potash

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What is 'lye' a generic term for?

Answer: Sodium hydroxide, potassium hydroxide, or a mixture of the two.

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What is the saturated solution of calcium hydroxide known as?

Answer: Limewater

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What is the chemical formula for sodium hydroxide?

Answer: NaOH

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What is the chemical formula for calcium hydroxide?

Answer: Ca(OH)₂

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Environmental Impact and Applications

Soils are defined as alkaline if their pH values are higher than 7.3.

Answer: True

Explanation: Alkaline soil is indeed defined by a pH value exceeding 7.3.

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Most plants prefer highly alkaline soil conditions for optimal growth.

Answer: False

Explanation: Most plants prefer mildly acidic soil (pH 6.0-6.8) for optimal growth, not highly alkaline conditions.

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An alkali lake forms when evaporation concentrates naturally occurring sulfate salts.

Answer: False

Explanation: Alkali lakes form due to the concentration of naturally occurring carbonate salts, not sulfate salts, through evaporation.

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Lake Magadi and Lake Turkana are examples of alkali lakes found in Kenya.

Answer: True

Explanation: The text explicitly lists Lake Magadi and Lake Turkana in Kenya as examples of alkali lakes.

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Cabbage and buffalo grass are examples of plants that prefer slightly basic soil.

Answer: True

Explanation: The text specifically mentions cabbage and buffalo grass as plants that prefer slightly basic soil conditions.

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Alkali lakes are also commonly referred to as salt lakes.

Answer: False

Explanation: Alkali lakes are also commonly referred to as soda lakes, not salt lakes, although they can be saline.

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Baldwin Lake in San Bernardino County, California, is cited as an example of an alkali lake.

Answer: True

Explanation: Baldwin Lake is indeed listed as an example of an alkali lake in the provided text.

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What pH value typically defines alkaline soil?

Answer: Higher than 7.3

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What is another name for an alkali lake?

Answer: Soda lake

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Which of the following lakes is mentioned as an example of an alkali lake?

Answer: Mono Lake

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What is the general pH preference for most plants regarding soil conditions?

Answer: Mildly acidic (pH 6.0-6.8)

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Which of the following plants is mentioned as preferring slightly basic soil?

Answer: Cabbage

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What type of salts are concentrated in an alkali lake due to evaporation?

Answer: Carbonate salts

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Which of the following is NOT an example of an alkali lake mentioned in the text?

Answer: Lake Victoria in Africa

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