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Study Guide: Understanding Dangerous Goods and HAZMAT Regulations

Cheat Sheet:
Understanding Dangerous Goods and HAZMAT Regulations Study Guide

Foundations of Dangerous Goods

A substance is classified as a dangerous good if it poses a risk to health, safety, property, or the environment during transport.

Answer: True

Explanation: Dangerous goods are defined by their potential to pose risks to health, safety, property, or the environment during the transportation process.

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Hazardous materials (HAZMAT) are a broader category than dangerous goods, encompassing all substances that pose risks.

Answer: False

Explanation: Hazardous materials (HAZMAT) are a subset of dangerous goods, specifically referring to substances that pose risks even when not actively being transported, such as hazardous waste.

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What defines a substance as a dangerous good according to transport regulations?

Answer: A substance that poses a risk to health, safety, property, or the environment during transport.

Explanation: Dangerous goods are broadly defined as substances posing risks to health, safety, property, or the environment during transport, encompassing a wide range of hazard types.

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How does the term 'hazardous materials' (HAZMAT) differ from the broader category of 'dangerous goods'?

Answer: HAZMAT is a subset of dangerous goods that pose risks even when not actively being transported.

Explanation: HAZMAT is a specific designation within dangerous goods, referring to materials that present risks beyond the transport phase, such as hazardous waste.

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Global Regulatory Landscape

The UN Recommendations on the Transport of Dangerous Goods are issued by the International Maritime Organization (IMO).

Answer: False

Explanation: The UN Recommendations on the Transport of Dangerous Goods are issued by the United Nations Economic and Social Council, serving as a foundational model for other regulatory schemes.

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The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) aims to create unique national classification and labeling standards for chemicals.

Answer: False

Explanation: The GHS aims to establish an internationally agreed-upon system for chemical classification and labeling, replacing disparate national standards with a unified approach.

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The International Civil Aviation Organization (ICAO) adapts UN recommendations for sea transport.

Answer: False

Explanation: The International Civil Aviation Organization (ICAO) adapts UN recommendations for air transport. The International Maritime Organization (IMO) adapts them for sea transport.

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REACH is a directive governing air transport of dangerous goods within the EU.

Answer: False

Explanation: REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) is a regulation concerning chemical substances within the EU, not specifically air transport of dangerous goods. Air transport is governed by regulations like ADR and IATA DGR.

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Which international body issues the foundational recommendations for the transport of dangerous goods?

Answer: The United Nations Economic and Social Council

Explanation: The UN Economic and Social Council develops the UN Recommendations on the Transport of Dangerous Goods, which form the basis for international and national regulations.

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What is the primary goal of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)?

Answer: To establish an internationally agreed-upon system for chemical classification and labeling.

Explanation: The GHS aims to create a unified global standard for classifying chemical hazards and communicating them through labels and safety data sheets.

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Classification, Identification, and Packaging

Dangerous goods are identified for transport by UN numbers and proper shipping names.

Answer: True

Explanation: UN numbers and proper shipping names are the primary identifiers assigned to dangerous goods for regulatory and safety purposes during transport.

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Class 1.4 explosives, such as ammunition, are characterized by a significant mass explosion hazard.

Answer: False

Explanation: Class 1.4 explosives, like ammunition, present a minor fire or projection hazard, not a significant mass explosion hazard, which is characteristic of Class 1.1.

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Class 2.2 gases are defined by their flammability.

Answer: False

Explanation: Class 2.2 gases are defined as Non-Flammable Gases, meaning they are neither flammable nor poisonous. Flammability is the defining characteristic of Class 2.1 gases.

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Packing Group III for Class 3 Flammable Liquids indicates the greatest degree of danger.

Answer: False

Explanation: Packing Group III indicates the least danger among the packing groups for Class 3 Flammable Liquids. Packing Group I signifies the greatest danger.

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White phosphorus is an example of a Class 4.2 spontaneously combustible substance.

Answer: True

Explanation: White phosphorus ignites spontaneously in air and is therefore classified under Class 4.2, Spontaneously Combustible materials.

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Class 5.2 substances are primarily oxidizing agents.

Answer: False

Explanation: Class 5.2 substances are Organic Peroxides. Class 5.1 substances are Oxidizing Agents.

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Class 6.2 substances are defined by their toxicity upon inhalation.

Answer: False

Explanation: Class 6.2 substances are Biohazardous materials, which are infectious. Class 6.1 substances are defined by their toxicity, including upon inhalation.

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Class 7 (Radioactive Substances) includes materials that emit ionizing radiation.

Answer: True

Explanation: Class 7 is designated for Radioactive Substances, which are materials that emit ionizing radiation.

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Class 8.2 classifies alkalis, such as sodium hydroxide.

Answer: True

Explanation: Class 8.2 is designated for corrosive alkalis, with sodium hydroxide being a prime example.

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Dry ice is an example of a Class 9 miscellaneous dangerous good.

Answer: True

Explanation: Dry ice (solid carbon dioxide) is classified under Class 9 (Miscellaneous Dangerous Goods) as it does not fit into the other eight hazard classes but still presents transport risks.

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Packing groups are assigned to dangerous goods to indicate the quantity of the substance being transported.

Answer: False

Explanation: Packing groups are assigned to indicate the degree of danger posed by a substance, which in turn dictates the required level of protective packaging.

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The UN 4G certification on a corrugated fiberboard box signifies it is certified for shipping four bottles of corrosive liquid, meeting standards for Packing Group III.

Answer: True

Explanation: A UN 4G certification indicates a doublewall corrugated fiberboard package with dividers, certified for performance standards, such as those required for shipping corrosive liquids in Packing Group III.

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Hydrogen peroxide is a common example of an oxidizing agent found in Class 5.1.

Answer: True

Explanation: Hydrogen peroxide is a common example of an oxidizing agent classified under Class 5.1.

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Mercuric chloride is classified as a poison under Class 6.1.

Answer: True

Explanation: Mercuric chloride is a toxic substance and is classified as a poison under Class 6.1.

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Compatibility group letters are assigned to flammable liquids to ensure proper packaging.

Answer: False

Explanation: Compatibility group letters are assigned to explosives to ensure proper segregation during transport, not to flammable liquids for packaging purposes.

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UN 1203 is the proper shipping name for MOTOR SPIRIT or GASOLINE or PETROL.

Answer: True

Explanation: UN 1203 is indeed the assigned UN number for MOTOR SPIRIT, GASOLINE, or PETROL.

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Class 4.3 Dangerous when Wet substances emit flammable gas or react violently with water.

Answer: True

Explanation: Class 4.3 substances are characterized by their dangerous reaction with water, either by emitting flammable gas or reacting violently.

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Class 8.1 classifies acids, such as sulfuric acid and hydrochloric acid.

Answer: True

Explanation: Class 8.1 is designated for corrosive acids, with sulfuric acid and hydrochloric acid being common examples.

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UN 3480 is the proper shipping name for LITHIUM METAL BATTERIES.

Answer: False

Explanation: UN 3480 is the proper shipping name for LITHIUM ION BATTERIES. UN 3090 is for LITHIUM METAL BATTERIES.

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Class 2.2 Non-Flammable Gases are neither flammable nor poisonous.

Answer: True

Explanation: Class 2.2 gases are defined by their non-flammable and non-poisonous characteristics.

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What two key pieces of information are assigned to dangerous goods for identification during transport?

Answer: UN numbers and proper shipping names

Explanation: UN numbers and proper shipping names are the standardized identifiers used for dangerous goods in transportation documentation and labeling.

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Which UN number is associated with MOTOR SPIRIT or GASOLINE or PETROL?

Answer: UN 1203

Explanation: UN 1203 is the designated UN number for MOTOR SPIRIT, GASOLINE, or PETROL.

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On what basis are dangerous goods divided into different classes for classification and labeling purposes?

Answer: By the specific chemical characteristics that produce the risk

Explanation: Dangerous goods are classified into nine main classes based on the inherent risks and chemical properties that make them hazardous.

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Which subdivision of Class 1 signifies an insensitive substance with a mass explosion hazard?

Answer: 1.5

Explanation: Class 1.5 is designated for insensitive substances that still present a mass explosion hazard, such as certain blasting agents.

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What hazard category does acetylene fall under in Class 2?

Answer: 2.1 Flammable Gas

Explanation: Acetylene is highly flammable and is classified as a Class 2.1 Flammable Gas.

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Which packing group for Class 3 Flammable Liquids is assigned to substances like kerosene and diesel?

Answer: Packing Group III

Explanation: Kerosene and diesel are assigned to Packing Group III for Class 3 Flammable Liquids, indicating a lower degree of danger compared to Packing Groups I and II.

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Which division of Class 4 includes substances that ignite spontaneously in air?

Answer: 4.2 Spontaneously Combustible

Explanation: Class 4.2 is designated for substances that are Spontaneously Combustible, meaning they ignite readily when exposed to air.

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What do substances classified under Class 5.2 primarily consist of?

Answer: Organic Peroxides

Explanation: Class 5.2 is exclusively for Organic Peroxides, which are a distinct category of hazardous substances.

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Which division of Class 6 includes substances liable to cause death or serious injury upon inhalation, ingestion, or skin absorption?

Answer: 6.1 Poison

Explanation: Class 6.1 is designated for poisons and toxic substances, defined by their potential to cause harm through various exposure routes.

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What characteristic defines substances belonging to Class 7?

Answer: They emit ionizing radiation.

Explanation: Class 7 is defined by the emission of ionizing radiation, characteristic of radioactive materials.

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Which of the following is a common example of an acid classified under Class 8.1?

Answer: Sulfuric acid

Explanation: Sulfuric acid is a common example of a corrosive acid classified under Class 8.1.

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What is the defining characteristic of substances placed in Class 9 (Miscellaneous) dangerous goods?

Answer: They do not fit into the other eight categories.

Explanation: Class 9 is a catch-all category for hazardous materials that do not meet the criteria for Classes 1 through 8 but still pose a risk during transport.

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What is the primary purpose of assigning packing groups to dangerous goods for transportation?

Answer: To indicate the degree of danger and required protective packaging

Explanation: Packing groups are assigned to dangerous goods to specify the level of danger and the corresponding protective packaging requirements for safe transport.

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Which packing group signifies the greatest danger and requires the most protective packaging?

Answer: Packing Group I

Explanation: Packing Group I represents the highest degree of danger among dangerous goods and mandates the most stringent protective packaging.

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What does the UN 4G certification on a corrugated fiberboard box indicate about its suitability for shipping?

Answer: It is a doublewall corrugated fiberboard package with dividers, certified for specific performance standards.

Explanation: A UN 4G marking signifies that a corrugated fiberboard box has met rigorous performance testing standards for the transport of dangerous goods.

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Which of the following is a common example of an oxidizing agent found in Class 5.1?

Answer: Ammonium nitrate

Explanation: Ammonium nitrate is a widely recognized example of an oxidizing agent classified under Class 5.1.

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Which of the following is a common example of an alkali classified under Class 8.2?

Answer: Sodium hydroxide

Explanation: Sodium hydroxide is a common example of a corrosive alkali classified under Class 8.2.

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What is the functional purpose of assigning compatibility group letters to explosive dangerous goods?

Answer: To facilitate their segregation during transport.

Explanation: Compatibility group letters are crucial for ensuring that different types of explosives are not stored or transported together, thereby preventing dangerous reactions.

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Which of the following is classified as a poison under Class 6.1?

Answer: Potassium cyanide

Explanation: Potassium cyanide is a toxic substance classified under Class 6.1 (Poisons).

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Which of the following is an example of a substance classified under Class 1.1 Explosives?

Answer: Trinitrotoluene (TNT)

Explanation: Trinitrotoluene (TNT) is a classic example of a Class 1.1 explosive, characterized by a mass explosion hazard.

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Which of the following materials is classified as dangerous when wet under Class 4.3?

Answer: Sodium

Explanation: Sodium is a metal that reacts violently with water, emitting flammable gas, and is classified under Class 4.3 (Dangerous when Wet).

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What does the UN 4G certification on a corrugated fiberboard box signify?

Answer: It is a doublewall corrugated fiberboard package with dividers, certified for performance.

Explanation: The UN 4G marking confirms that the corrugated fiberboard box meets specific performance standards for the transport of dangerous goods, typically involving doublewall construction and dividers.

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Which of the following gases is classified as poisonous under Class 2.3?

Answer: Chlorine

Explanation: Chlorine is a toxic gas and is classified under Class 2.3 (Poisonous Gas).

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Safety Protocols and Emergency Preparedness

Individuals handling dangerous goods are never required to wear protective equipment.

Answer: False

Explanation: Personnel handling dangerous goods are often required to wear appropriate protective equipment to mitigate risks.

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Occupational exposure limits are set to ensure that individuals do not exceed safe exposure levels when working with dangerous goods.

Answer: True

Explanation: Occupational exposure limits are established to protect workers by defining the maximum permissible levels of exposure to hazardous substances.

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A transport document for dangerous goods only needs the shipper's name and address.

Answer: False

Explanation: Transport documents for dangerous goods require more than just shipper and consignee details; they must include a detailed description of each dangerous good, its classification, and emergency contact information.

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Written instructions for dangerous goods shipments are meant for the consignee's review upon delivery.

Answer: False

Explanation: Written instructions carried with dangerous goods shipments are intended to assist first responders and drivers during emergency situations, not solely for consignee review.

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The image depicts emergency medical technicians undergoing training for hazardous material and toxic contamination situations.

Answer: True

Explanation: The image shows emergency medical technicians in specialized suits, indicating they are participating in training for hazardous material and toxic contamination scenarios.

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The Emergency Response Guidebook (ERG) provides first responders with essential information about hazardous materials to understand appropriate safety procedures during emergencies.

Answer: True

Explanation: The ERG is a critical resource for first responders, offering guidance on identifying hazardous materials and implementing safety measures during emergencies.

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What is a common safety measure for personnel working with dangerous goods?

Answer: Wearing protective equipment.

Explanation: Wearing appropriate personal protective equipment (PPE) is a fundamental safety measure for individuals handling dangerous goods.

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What is the purpose of occupational exposure limits for personnel working with hazardous materials?

Answer: To ensure personnel do not exceed safe exposure levels.

Explanation: Occupational exposure limits are established to safeguard workers by defining the maximum permissible levels of exposure to hazardous substances in the workplace.

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What essential information must be included on a transport document for dangerous goods?

Answer: Shipper's and consignee's details, description of goods, and emergency contact.

Explanation: A transport document for dangerous goods must contain comprehensive information, including shipper/consignee details, a precise description of the goods, and emergency contact information.

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What is the intended purpose of the written instructions carried with dangerous goods shipments?

Answer: To assist in emergency situations involving the goods.

Explanation: Written instructions accompanying dangerous goods shipments are designed to provide critical guidance for managing emergencies related to those materials.

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How does the Emergency Response Guidebook (ERG) assist first responders when dealing with hazardous materials?

Answer: By enabling identification of substances and understanding of safety procedures.

Explanation: The ERG is designed to help first responders quickly identify hazardous materials and access essential safety information and emergency procedures.

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What activity is depicted in the image showing emergency medical technicians in different colored suits?

Answer: Undergoing training for hazardous material situations.

Explanation: The image shows emergency medical technicians in protective gear, indicative of training exercises for hazardous material incidents.

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Hazard Communication Systems

NFPA 704 diamond markings are used for labeling consumer products containing hazardous materials.

Answer: False

Explanation: NFPA 704 diamond markings are primarily used for labeling fixed facilities to communicate hazards to emergency responders, not typically for consumer products.

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The skull pictogram in the GHS system indicates poisonous substances.

Answer: True

Explanation: The skull and crossbones pictogram is used in the GHS system to denote poisonous or toxic substances.

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In the NFPA 704 system, the color red signifies flammability.

Answer: True

Explanation: In the NFPA 704 hazard identification system, the color red is used to indicate the flammability hazard.

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The Hazchem warning plate system provides crucial information to emergency services regarding how to respond to incidents involving dangerous goods.

Answer: True

Explanation: The Hazchem warning plate system is designed to provide emergency responders with immediate, actionable information for incidents involving hazardous materials.

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The color orange in the NFPA 704 system indicates the hazard of explosives.

Answer: True

Explanation: In the NFPA 704 system, the color orange signifies the hazard of explosives.

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What specific hazard does the skull pictogram, part of the GHS system, indicate?

Answer: Poisonous substances

Explanation: The skull pictogram in the GHS system is universally recognized as indicating poisonous or toxic substances.

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In the NFPA 704 hazard identification system, what hazard does the color red represent?

Answer: Flammability

Explanation: Within the NFPA 704 system, the color red is designated to indicate the flammability hazard of a substance.

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What historical reason is given for the use of green in the NFPA 704 system for nonflammable and nontoxic gases?

Answer: It was the color of compressed air vessels in France after WWII.

Explanation: The use of green for nonflammable and nontoxic gases in the NFPA 704 system originates from the historical practice of painting compressed air vessels in France after World War II.

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What hazard is indicated by the color orange in the NFPA 704 hazard identification system?

Answer: Explosives

Explanation: In the NFPA 704 system, the color orange is used to denote the hazard associated with explosives.

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Jurisdictional Regulations and Historical Context

Regulations for hazardous materials are identical regardless of whether they are in a workplace or being transported.

Answer: False

Explanation: Regulations for hazardous materials can vary significantly depending on the context, such as their use in a workplace versus their transport or sale to consumers.

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The September 11, 2001 attacks led to a decrease in funding for hazmat capabilities in the US.

Answer: False

Explanation: Following the September 11, 2001 attacks, funding for hazmat capabilities in the US increased due to heightened security concerns.

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The Environmental Protection Agency (EPA) is primarily responsible for regulating the transport of dangerous goods in the US.

Answer: False

Explanation: The Pipeline and Hazardous Materials Safety Administration (PHMSA) is primarily responsible for regulating the transport of dangerous goods in the US, while the EPA focuses on environmental protection and waste management.

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In the U.S., hazardous materials in transport are marked with UN numbers, following the UN model.

Answer: True

Explanation: The U.S. follows the UN model for marking hazardous materials in transport, utilizing UN numbers for identification.

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The Pennsylvania Tunnel Hazmat Restrictions Sign indicates which hazard classes are permitted in the tunnel.

Answer: False

Explanation: The Pennsylvania Tunnel Hazmat Restrictions Sign indicates which DOT hazard classes are restricted from entering the tunnel, rather than which are permitted.

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Australia's Australian Dangerous Goods Code aligns with international import/export standards and the UN Recommendations on the Transport of Dangerous Goods.

Answer: True

Explanation: Australia's Dangerous Goods Code is harmonized with international standards, including the UN Recommendations, to facilitate global trade and safety.

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In Canada, provinces are primarily responsible for regulating air transport of dangerous goods.

Answer: False

Explanation: In Canada, the federal government primarily regulates air transport of dangerous goods, while provinces typically regulate road transport.

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In New Zealand, drivers who transport dangerous goods commercially must obtain a 'D' endorsement on their driver's license.

Answer: True

Explanation: New Zealand requires drivers transporting dangerous goods commercially to obtain a specific 'D' endorsement on their license.

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Regulations for hazardous materials can differ based on what factor?

Answer: Their context of use (workplace, transport, consumer)

Explanation: Regulatory requirements for hazardous materials vary depending on whether they are being used in a workplace, transported, or sold for consumer use.

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What impact did the September 11, 2001 attacks have on the funding and focus of hazmat capabilities in the United States?

Answer: Funding increased, and focus on capabilities was enhanced.

Explanation: The 9/11 attacks led to increased investment and a heightened focus on enhancing hazmat capabilities in the U.S. due to security concerns.

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Which U.S. federal agency is responsible for regulating workplace safety and incident response concerning hazardous materials?

Answer: Occupational Safety and Health Administration (OSHA)

Explanation: OSHA is the primary U.S. agency responsible for ensuring safe workplaces, including those involving hazardous materials, and overseeing incident response protocols.

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How do UN numbers aid first responders in the U.S. when dealing with hazardous materials in transport?

Answer: They allow quick access to critical information in resources like the Emergency Response Guidebook.

Explanation: UN numbers serve as a quick reference point, enabling first responders to rapidly access vital safety information for specific hazardous materials through guides like the ERG.

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What information is conveyed by the Pennsylvania Tunnel Hazmat Restrictions Sign?

Answer: The DOT hazard classes restricted within the tunnel.

Explanation: These signs clearly indicate which DOT hazard classes of materials are prohibited from entering the tunnel for safety reasons.

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In Canada, which level of government primarily regulates the road transport of dangerous goods?

Answer: Provincial governments

Explanation: In Canada, provincial governments hold the primary responsibility for regulating the road transport of dangerous goods, although they often align with federal standards.

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What specific endorsement is required for New Zealand drivers who transport dangerous goods commercially?

Answer: A 'D' endorsement

Explanation: New Zealand requires drivers who transport dangerous goods commercially to obtain a 'D' endorsement on their driver's license.

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Which U.S. federal agency is responsible for regulating the transport of dangerous goods?

Answer: Pipeline and Hazardous Materials Safety Administration (PHMSA)

Explanation: The PHMSA is the U.S. federal agency tasked with regulating the safe transportation of hazardous materials.

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