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Study Guide: Fiberglass: Properties, Applications, and Safety

Cheat Sheet:
Fiberglass: Properties, Applications, and Safety Study Guide

I. Fundamentals of Fiberglass Composites

Fiberglass, a composite material, is exclusively composed of glass fibers embedded within a thermoplastic matrix.

Answer: False

Explanation: The assertion is incorrect; while fiberglass utilizes glass fibers, the matrix is typically a thermoset polymer, not exclusively thermoplastic. The composition involves glass fibers embedded in a polymer matrix.

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Glass-reinforced plastic (GRP) is an alternative name for fiberglass.

Answer: True

Explanation: The provided source material explicitly states that Glass-Reinforced Plastic (GRP) is recognized as an alternative nomenclature for fiberglass.

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The plastic matrix in fiberglass primarily serves to add color to the composite material.

Answer: False

Explanation: The primary role of the plastic matrix in fiberglass is to hold the glass fibers in place, prevent buckling, and transfer loads, rather than merely providing color.

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What is the primary composition of fiberglass?

Answer: A composite material with glass fibers embedded in a plastic matrix.

Explanation: Fiberglass is fundamentally a composite material consisting of glass fibers embedded within a polymer matrix.

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Which of the following is NOT an alternative name for fiberglass mentioned in the text?

Answer: Glass-fiber composite material (GFCM)

Explanation: While GRP, GFRP, and FRP are recognized alternative names, 'Glass-fiber composite material (GFCM)' is not explicitly listed as an alternative nomenclature in the provided text.

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What is the main role of the plastic matrix in a fiberglass composite?

Answer: To hold the glass fibers in place and prevent buckling.

Explanation: The plastic matrix serves the critical function of binding the glass fibers together, maintaining their orientation, and preventing them from buckling under load.

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II. Historical Evolution and Innovations

The earliest known patent for glass fibers was granted in the 20th century.

Answer: False

Explanation: The earliest known patent for glass fibers was granted in the 19th century, specifically in 1880 to Hermann Hammesfahr.

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Games Slayter discovered the mass production of glass strands by directing compressed air at molten glass.

Answer: True

Explanation: Games Slayter's discovery in 1932 involved directing a jet of compressed air at a stream of molten glass, which resulted in the formation of fine fibers, leading to mass production methods.

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Owens Corning began producing their patented 'Fiberglas' in 1936 after adapting Games Slayter's glass wool production method.

Answer: True

Explanation: Following Games Slayter's innovations, Owens Corning adapted the glass wool production method to develop and produce their patented 'Fiberglas' starting in 1936.

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The original 'Fiberglas' product was primarily valued for its strength as a structural material.

Answer: False

Explanation: The initial 'Fiberglas' product, developed as glass wool, was primarily valued for its insulating properties due to trapped gas, not its structural strength.

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DuPont developed the first suitable resin for creating fiberglass composite materials in 1936.

Answer: True

Explanation: The development of a suitable resin by DuPont in 1936 was a critical advancement, enabling the transformation of fiberglass from an insulating material into a structural composite.

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Ray Greene successfully commercialized the first composite boat in 1937.

Answer: False

Explanation: While Ray Greene produced the first composite boat in 1937, it did not achieve commercial success at that time due to issues with the brittleness of the plastic matrix used.

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In the 1950s, fiberglass found early civilian applications in the marine and automotive industries.

Answer: True

Explanation: The 1950s marked the emergence of significant civilian applications for fiberglass, particularly within the marine sector for boat construction and the automotive industry for vehicle components.

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Who received the earliest known patent for glass fibers in the United States?

Answer: Hermann Hammesfahr

Explanation: Hermann Hammesfahr, a Prussian inventor, was granted the earliest known patent for glass fibers in the United States in 1880.

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How did Games Slayter discover the mass production method for glass strands?

Answer: By directing compressed air at a stream of molten glass.

Explanation: Games Slayter's serendipitous discovery involved directing a jet of compressed air at a stream of molten glass, producing fine fibers suitable for mass production.

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What was the initial purpose of Owens Corning's 'Fiberglas' product?

Answer: As an effective insulating material due to trapped gas.

Explanation: The original 'Fiberglas' product, developed as glass wool, was primarily intended and valued for its excellent insulating capabilities derived from trapped gas.

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What innovation in 1936 was crucial for transforming fiberglass into a structural material?

Answer: The development of a suitable resin by DuPont.

Explanation: The development of a suitable resin by DuPont in 1936 was pivotal, enabling the combination of glass fibers with plastic to create strong, structural composite materials.

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Why did the first composite boat project in 1937 face challenges?

Answer: Brittleness of the plastic used.

Explanation: Ray Greene's 1937 composite boat project encountered difficulties primarily due to the brittleness of the plastic matrix employed at that time.

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Which industries saw the first major civilian applications for fiberglass in the 1950s?

Answer: Marine and automotive.

Explanation: The 1950s witnessed the initial widespread civilian adoption of fiberglass in the marine industry for boat hulls and in the automotive sector for vehicle bodies.

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III. Material Science and Manufacturing

Silica sand is a raw material NOT used in the manufacturing of glass fibers for reinforcement.

Answer: False

Explanation: Silica sand is, in fact, a primary raw material commonly used in the melting furnaces for the production of glass fibers.

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In fiberglass manufacturing, 'bushings' are used to melt the raw materials.

Answer: False

Explanation: 'Bushings' in fiberglass manufacturing are not used for melting raw materials; rather, they function as spinnerets, extruding molten glass through fine orifices to form filaments.

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The 'sizing' applied to glass filaments protects them and helps them bond with the plastic matrix.

Answer: True

Explanation: Sizing, a chemical coating applied during formation, serves to protect the delicate glass filaments and crucially ensures their adhesion to the plastic matrix, facilitating effective load transfer.

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Rovings are formed by bundling a large number of individual glass filaments together.

Answer: True

Explanation: Rovings are indeed formed by consolidating numerous individual glass filaments into larger strands, which are then used in various composite manufacturing processes.

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Chopped strand mat (CSM) consists of long, continuous strands of glass fiber.

Answer: False

Explanation: Chopped strand mat (CSM) is characterized by short, randomly oriented strands of glass fiber, not long, continuous ones.

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Defects on the surface of glass fibers increase their tensile strength.

Answer: False

Explanation: Surface defects on glass fibers act as stress concentrators, thereby reducing their tensile strength; defect-free surfaces are critical for achieving high strength.

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The high aspect ratio of glass fibers makes them appear strong in compression.

Answer: False

Explanation: The high aspect ratio (long and narrow shape) of glass fibers renders them susceptible to buckling under compressive loads, making them appear weak in compression despite their axial strength.

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Fiberglass resins typically expand as they cure.

Answer: False

Explanation: Many fiberglass resins, such as polyester and epoxy, characteristically contract, rather than expand, during the curing process.

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E-glass is the most common type of glass fiber used in fiberglass manufacturing.

Answer: True

Explanation: E-glass, an alumino-borosilicate glass, is the most widely utilized type of glass fiber in fiberglass production due to its favorable balance of properties and cost-effectiveness.

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E-glass is highly resistant to chloride ion attack, making it ideal for marine applications.

Answer: False

Explanation: A notable limitation of E-glass is its susceptibility to chloride ion attack, which can be problematic in marine environments, despite its widespread use.

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S-glass is chosen for applications requiring high tensile strength and stiffness.

Answer: True

Explanation: S-glass, an alumino silicate glass, is specifically selected for applications demanding superior mechanical performance, characterized by high tensile strength and modulus (stiffness).

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C-glass and T-glass are primarily known for their high tensile strength.

Answer: False

Explanation: C-glass and T-glass are primarily recognized for their excellent resistance to chemical attack, rather than high tensile strength.

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The filament winding process involves pulling fibers through a die to create composite profiles.

Answer: False

Explanation: Filament winding involves winding resin-impregnated fibers onto a rotating mandrel to form hollow structures, distinct from processes that pull material through a die to create profiles.

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In filament winding, a high wind angle primarily enhances longitudinal tensile strength.

Answer: False

Explanation: In filament winding, a high wind angle primarily contributes to hoop strength (circumferential resistance), while lower angles are more effective for enhancing longitudinal tensile strength.

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A release agent is used in hand lay-up to saturate the fiberglass with resin.

Answer: False

Explanation: A release agent is applied to the mold surface in hand lay-up to facilitate the easy removal of the cured part, not to saturate the fiberglass with resin.

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Spray lay-up uses a gun to simultaneously chop glass fibers and spray them with resin.

Answer: True

Explanation: The spray lay-up process utilizes a specialized gun that simultaneously chops glass fibers and applies them along with resin onto the mold surface, enabling efficient coverage.

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Pultrusion involves pulling composite materials through a die, similar to extrusion.

Answer: False

Explanation: Pultrusion involves pulling resin-impregnated fibers through a die to form continuous profiles, whereas extrusion involves pushing material through a die.

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Which of the following is a common raw material used in melting furnaces for glass fiber production?

Answer: Limestone

Explanation: Limestone is among the common raw materials, alongside silica sand and other minerals, heated in furnaces for the production of glass fibers.

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What is the primary function of 'sizing' in fiberglass production?

Answer: To protect filaments and ensure bonding with the resin matrix.

Explanation: Sizing serves a dual purpose: it protects the delicate glass filaments during handling and processing, and it promotes strong adhesion between the filaments and the resin matrix.

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How are 'rovings' measured in terms of density?

Answer: By weight in yards per pound (yield) or grams per kilometer (tex).

Explanation: The density or 'weight' of rovings is quantified by systems such as 'yield' (yards per pound) or 'tex' (grams per kilometer), indicating the mass per unit length.

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What is 'Chopped Strand Mat' (CSM)?

Answer: A reinforcement material with randomly oriented short glass strands.

Explanation: Chopped Strand Mat (CSM) is a reinforcement material consisting of short, randomly oriented glass fiber strands bound together. It is frequently used in hand lay-up processes due to its conformability to complex shapes.

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Why are defect-free surfaces critical for the high strength of structural glass fibers?

Answer: Defects act as stress concentrators, reducing tensile strength.

Explanation: Surface defects on glass fibers act as points where stress concentrates, thereby limiting the fiber's overall tensile strength. Near-perfect surfaces are essential for maximizing this strength.

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What causes glass fibers to appear weak in compression despite their axial strength?

Answer: Their high aspect ratio leading to buckling.

Explanation: Glass fibers possess a high aspect ratio, meaning they are long and thin. This geometry makes them prone to buckling under compressive loads, leading to an apparent weakness in compression.

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What is a characteristic behavior of many fiberglass resins during the curing process?

Answer: Contraction

Explanation: A common characteristic of many thermosetting resins used in fiberglass, such as polyester and epoxy, is contraction as they cure, leading to internal stresses.

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Which type of glass fiber is most commonly used due to its balance of properties and cost?

Answer: E-glass

Explanation: E-glass is the most prevalent type of glass fiber in fiberglass manufacturing, offering a desirable combination of performance characteristics and economic viability.

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What is a significant limitation of E-glass in marine environments?

Answer: Its susceptibility to chloride ion attack.

Explanation: E-glass exhibits a vulnerability to chloride ion attack, which can be a significant limitation in marine applications where prolonged exposure to saltwater occurs.

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For which type of glass fiber are high tensile strength and high modulus (stiffness) the defining characteristics?

Answer: S-glass

Explanation: S-glass is distinguished by its exceptionally high tensile strength and high modulus, making it suitable for applications demanding maximum mechanical performance.

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C-glass and T-glass are primarily valued for their:

Answer: Exceptional resistance to chemical attack.

Explanation: C-glass and T-glass are primarily recognized for their superior resistance to chemical degradation, making them suitable for applications where chemical inertness is paramount.

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Which manufacturing process involves pulling resin-impregnated fibers through a die to create continuous profiles?

Answer: Pultrusion

Explanation: Pultrusion is a manufacturing process where resin-impregnated fibers are continuously pulled through a shaped die to form constant cross-section profiles.

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IV. Performance Characteristics and Applications

Fiberglass is generally more expensive and less flexible than carbon fiber.

Answer: False

Explanation: Contrary to the statement, fiberglass is typically less expensive and more flexible when compared to carbon fiber, making it a more accessible material for many applications.

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A significant advantage of fiberglass compared to many metallic materials is its transparency to electromagnetic radiation.

Answer: True

Explanation: Fiberglass exhibits transparency to electromagnetic radiation, a property that distinguishes it from many metals and makes it advantageous for applications such as radomes and antenna shrouds.

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Fiberglass is unsuitable for manufacturing boat hulls due to its poor moldability.

Answer: False

Explanation: Fiberglass is highly suitable for manufacturing boat hulls precisely because of its excellent moldability, allowing for complex shapes and efficient production.

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Combining fiberglass with resin significantly enhanced its insulating properties.

Answer: False

Explanation: The combination of fiberglass with resin replaced the insulating trapped gas with plastic, thereby reducing its insulating properties while significantly enhancing its strength and structural capabilities.

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The orientation of glass fibers within the plastic matrix does not affect the composite's stiffness and strength.

Answer: False

Explanation: The orientation of glass fibers is a critical factor that precisely controls the composite's stiffness and strength, allowing for tailored material properties.

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Fiberglass composites can lose structural integrity in high temperatures above 180°C due to resin degradation.

Answer: True

Explanation: Above approximately 180°C, the resin component of fiberglass composites is susceptible to thermal degradation, which can compromise the structural integrity of the material.

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A Polyester and Continuous Rovings Laminate (70% E-glass) has a tensile strength comparable to unreinforced Polyester resin.

Answer: False

Explanation: A laminate composed of 70% E-glass continuous rovings exhibits significantly higher tensile strength compared to unreinforced polyester resin, demonstrating the substantial reinforcing effect of the glass fibers.

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During World War II, fiberglass was used for aircraft radomes because it blocked microwaves.

Answer: False

Explanation: Fiberglass was utilized for aircraft radomes during WWII precisely because it is transparent to microwaves, allowing radar signals to pass through unimpeded.

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Fiberglass is used for shrouding antennas because it significantly interferes with radio waves.

Answer: False

Explanation: Fiberglass is employed for shrouding antennas due to its radio frequency (RF) permeability and low signal attenuation, meaning it minimally interferes with radio waves.

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Helmets and goaltenders' masks are examples of protective gear that commonly use fiberglass.

Answer: True

Explanation: Due to its favorable strength-to-weight ratio, fiberglass is frequently incorporated into protective equipment such as helmets and specialized masks for sports like hockey and baseball.

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Fiberglass storage tanks typically have a capacity limit of around 30 tonnes.

Answer: False

Explanation: Fiberglass storage tanks can be manufactured to accommodate significantly larger volumes, often exceeding 30 tonnes, with capacities reaching up to approximately 300 tonnes.

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Fiberglass tanks are often used for chemical storage due to the inertness of the glass fibers themselves.

Answer: False

Explanation: While fiberglass tanks are used for chemical storage, their suitability stems primarily from the chemical resistance of the plastic liner (e.g., polypropylene), not solely the inertness of the glass fibers themselves.

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Glass-reinforced plastics are used in house building for components like roofing laminates and chimneys.

Answer: True

Explanation: Glass-reinforced plastics (GRP) find application in residential construction for elements such as roofing laminates, chimneys, window frames, and decorative architectural features.

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Fiberglass offers installation advantages over wood or metal due to its higher weight and complexity.

Answer: False

Explanation: Fiberglass offers installation advantages over wood or metal primarily due to its lower weight and ease of handling, which can simplify and expedite construction processes.

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Fiberglass rods are used in oil and gas rod pumping due to their high strength-to-weight ratio and elastic stretch.

Answer: True

Explanation: In oil and gas operations, fiberglass rods are employed in rod pumping systems owing to their superior tensile strength-to-weight ratio and significant elastic stretch, which enhances operational efficiency.

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Fiberglass rods used in oil and gas applications can withstand significant compressive forces.

Answer: False

Explanation: A critical limitation of fiberglass rods in oil and gas applications is their inability to withstand substantial compressive forces; they must be maintained under tension to prevent failure.

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GRP and GRE pipes are suitable for applications like desalination and firewater systems.

Answer: True

Explanation: Pipes manufactured from Glass Reinforced Plastic (GRP) and Glass Reinforced Epoxy (GRE) are well-suited for demanding applications including desalination plants and firewater systems, owing to their durability and resistance properties.

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Compared to carbon fiber, fiberglass is generally considered:

Answer: Less expensive and more flexible.

Explanation: Fiberglass typically presents a more economical and flexible alternative when contrasted with carbon fiber.

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Which property makes fiberglass advantageous over many metals for applications involving radio waves?

Answer: Transparency to electromagnetic radiation.

Explanation: Fiberglass's transparency to electromagnetic radiation is a key advantage over many metals, enabling its use in radar and communication systems.

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According to the source, which of these is a common application of fiberglass?

Answer: Structural components in aircraft.

Explanation: Fiberglass is utilized in various structural applications, including components within aircraft, due to its strength-to-weight ratio and moldability.

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How is the stiffness and strength of fiberglass primarily controlled?

Answer: By the orientation of the glass fibers within the plastic matrix.

Explanation: The directional stiffness and strength of fiberglass composites are precisely controlled by orienting the glass fibers within the plastic matrix, often through layering.

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At what temperature range does the resin component of fiberglass composites typically begin to degrade?

Answer: Above 180°C

Explanation: The resin matrix in fiberglass composites is susceptible to thermal degradation, typically beginning to lose structural integrity at temperatures exceeding approximately 180°C.

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How does the tensile strength of a 70% E-glass continuous rovings laminate compare to unreinforced Polyester resin?

Answer: It is significantly higher.

Explanation: A laminate reinforced with 70% E-glass continuous rovings exhibits a substantially higher tensile strength (e.g., 800 MPa) compared to unreinforced polyester resin (e.g., 55 MPa).

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Why was fiberglass chosen for aircraft radomes during WWII?

Answer: Its ability to remain transparent to microwaves.

Explanation: Fiberglass was selected for aircraft radomes during World War II due to its critical property of being transparent to microwaves, which is essential for radar system functionality.

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What property makes fiberglass suitable for shrouding antennas in telecommunications?

Answer: Radio frequency (RF) permeability.

Explanation: Fiberglass's radio frequency (RF) permeability, meaning it allows radio waves to pass through with minimal interference, makes it ideal for antenna shrouds.

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Why are fiberglass rods advantageous in oil and gas rod pumping systems?

Answer: They offer superior elastic stretch compared to steel.

Explanation: Fiberglass rods are advantageous in oil and gas rod pumping due to their high strength-to-weight ratio and greater elastic stretch compared to steel, enhancing lifting efficiency.

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What is a critical weakness of fiberglass rods in oil and gas applications?

Answer: Inability to withstand compression.

Explanation: A significant limitation of fiberglass rods is their poor performance under compression; they must be kept under tension to avoid failure.

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V. Occupational Health and Safety

Inhalation of airborne fibers is a primary route of workplace exposure to fiberglass.

Answer: True

Explanation: Workplace exposure to fiberglass commonly occurs through inhalation of airborne fibers, alongside direct skin and eye contact during fabrication, installation, or removal processes.

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Styrene vapors released during fiberglass curing can irritate the eyes but not the respiratory tract.

Answer: False

Explanation: Styrene vapors released during fiberglass resin curing are known irritants to both the eyes and the respiratory tract.

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Skin contact with fiberglass fibers typically causes numbness.

Answer: False

Explanation: Skin contact with fiberglass fibers typically results in irritation and itching, not numbness.

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Animal experiments have shown fiberglass exposure can lead to lung inflammation and fibrosis.

Answer: True

Explanation: Studies involving animal models have indicated that exposure to fiberglass fibers can induce adverse pulmonary effects, including inflammation and fibrosis.

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The IARC classifies commonly used insulation glass wools as definitely carcinogenic to humans.

Answer: False

Explanation: By 2001, the International Agency for Research on Cancer (IARC) classified commonly used insulation glass wools as 'not classifiable as to carcinogenicity to humans' (Group 3).

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Cancer warning labels are still required for biosoluble fiber glass insulation in the US under federal law.

Answer: False

Explanation: Reflecting updated scientific assessments, cancer warning labels are generally no longer required for biosoluble fiber glass insulation in the US under federal law.

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NIOSH recommends a higher exposure limit for respirable fiberglass dust than OSHA's PEL.

Answer: False

Explanation: NIOSH generally recommends stricter exposure limits for fiberglass dust than OSHA's PEL, advocating for lower concentrations to ensure worker safety.

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Longer, thinner, and more durable fibers are less potent in causing damage.

Answer: False

Explanation: Conversely, longer, thinner, and more durable (biopersistent) fibers are generally considered more potent in inducing toxic and genetic effects.

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Reactive oxygen species (ROS) generated by fiberglass fibers can damage DNA.

Answer: True

Explanation: The generation of reactive oxygen species (ROS) by fiberglass fibers is a primary mechanism through which they can induce cellular damage, including DNA damage and chromosomal abnormalities.

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What health hazard is associated with styrene vapors released during fiberglass resin curing?

Answer: Respiratory tract irritation

Explanation: Styrene vapors emitted during the curing of fiberglass resins can cause irritation to the respiratory tract and mucous membranes.

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Which classification did the IARC give to commonly used insulation glass wools regarding carcinogenicity by 2001?

Answer: Not classifiable as to carcinogenicity to humans (Group 3)

Explanation: By 2001, the International Agency for Research on Cancer (IARC) classified commonly used insulation glass wools as 'not classifiable as to carcinogenicity to humans' (Group 3), indicating insufficient evidence for human carcinogenicity.

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What is the OSHA Permissible Exposure Limit (PEL) for total fiberglass dust over an 8-hour workday?

Answer: 15 mg/m³

Explanation: The Occupational Safety and Health Administration (OSHA) sets the Permissible Exposure Limit (PEL) for total fiberglass dust at 15 mg/m³ over an 8-hour workday.

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What mechanism is primarily responsible for the genetic and toxic effects of fiberglass fibers?

Answer: Stimulation of reactive oxygen species (ROS) production.

Explanation: The generation of reactive oxygen species (ROS) by fiberglass fibers is a primary mechanism through which they can induce cellular damage, including DNA damage and chromosomal abnormalities.

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