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Study Guide: Understanding Stratospheric Ozone Depletion

Cheat Sheet:
Understanding Stratospheric Ozone Depletion Study Guide

Ozone Layer Fundamentals

Ozone depletion refers solely to the reduction of ozone in the Earth's upper atmosphere, with no significant localized decreases observed.

Answer: False

Explanation: Ozone depletion involves both a general reduction in stratospheric ozone and significant localized decreases, particularly in polar regions (the ozone hole), as well as springtime tropospheric depletion events.

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The ozone-oxygen cycle in the stratosphere involves atomic oxygen (O), diatomic oxygen (O2), and triatomic oxygen (O3).

Answer: True

Explanation: The continuous formation and destruction of ozone in the stratosphere occur through the ozone-oxygen cycle, involving O, O2, and O3 molecules interacting via photochemical processes.

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Ozone is formed in the stratosphere when O2 molecules absorb low-energy visible light.

Answer: False

Explanation: Ozone (O3) is formed when O2 molecules absorb high-energy UVC photons, splitting into atomic oxygen radicals (O), which then combine with other O2 molecules.

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The ozone layer protects the Earth by absorbing most of the Sun's harmful UVB ultraviolet radiation.

Answer: True

Explanation: The ozone layer acts as a natural shield by absorbing the majority of harmful UVB ultraviolet radiation, preventing it from reaching the Earth's surface.

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The Dobson Unit (DU) is the standard measurement for total ozone column amounts.

Answer: True

Explanation: The Dobson Unit (DU) is the conventional unit used to measure the total amount of ozone in a vertical column of the atmosphere.

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What is the difference between stratospheric and tropospheric ozone depletion?

Answer: Stratospheric depletion thins the ozone layer in the upper atmosphere; tropospheric depletion occurs in the lower atmosphere, often in polar regions.

Explanation: Stratospheric ozone depletion refers to the thinning of the protective ozone layer, primarily caused by ODS. Tropospheric ozone depletion is a distinct phenomenon occurring in the lower atmosphere, often linked to specific polar conditions.

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How does the ozone layer's absorption of UV radiation influence stratospheric temperatures?

Answer: It is a primary source of heat for the stratosphere.

Explanation: The absorption of UV radiation, particularly UVB, by ozone molecules is the principal mechanism that heats the stratosphere, maintaining its characteristic temperature profile.

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What is the difference between stratospheric and tropospheric ozone depletion?

Answer: Stratospheric depletion thins the ozone layer in the upper atmosphere; tropospheric depletion occurs in the lower atmosphere, often in polar regions.

Explanation: Stratospheric ozone depletion refers to the thinning of the protective ozone layer, primarily caused by ODS. Tropospheric ozone depletion is a distinct phenomenon occurring in the lower atmosphere, often linked to specific polar conditions.

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How does the ozone layer's absorption of UV radiation influence stratospheric temperatures?

Answer: It is a primary source of heat for the stratosphere.

Explanation: The absorption of UV radiation, particularly UVB, by ozone molecules is the principal mechanism that heats the stratosphere, maintaining its characteristic temperature profile.

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Ozone Depleting Substances (ODS)

Chlorofluorocarbons (CFCs) are identified as the primary manufactured chemicals responsible for ozone depletion.

Answer: True

Explanation: Halocarbons, such as CFCs and HCFCs, are the primary manufactured chemicals responsible for stratospheric ozone depletion due to their ability to release catalytic halogen atoms.

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Chlorine and bromine atoms are the most effective halogen catalysts for ozone destruction in the stratosphere.

Answer: True

Explanation: Chlorine and bromine atoms are highly effective catalysts for ozone destruction because they remain reactive in the stratosphere for extended periods, participating in numerous catalytic cycles.

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CFCs contribute to global warming because they are potent greenhouse gases.

Answer: True

Explanation: Many CFCs possess strong greenhouse gas properties, meaning their emissions contribute significantly to global warming in addition to their ozone-depleting effects.

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The increase in CFC-113a's atmospheric abundance is significant because it is a known ozone-depleting substance whose source is unclear.

Answer: True

Explanation: The rising atmospheric concentration of CFC-113a is concerning because it is an ozone-depleting substance, and its continued increase suggests emissions from unknown or potentially illegal sources.

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Greenfreeze technology uses hydrocarbon refrigerants, making it environmentally friendly.

Answer: True

Explanation: Greenfreeze technology utilizes hydrocarbon refrigerants, which are considered ozone-safe and have low global warming potential, offering an environmentally sound alternative to CFCs and HFCs.

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What is the common misconception regarding the weight of CFC molecules and their ability to reach the stratosphere?

Answer: CFC molecules are heavier than air and thus cannot ascend to the stratosphere.

Explanation: A common misconception is that CFC molecules, being heavier than air, cannot reach the stratosphere; however, atmospheric mixing allows them to ascend and participate in stratospheric chemical reactions.

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What makes Greenfreeze technology significant?

Answer: It uses hydrocarbon refrigerants that are ozone-safe and have low global warming potential.

Explanation: Greenfreeze technology is significant because it employs hydrocarbon refrigerants, which are environmentally benign alternatives to ozone-depleting substances and potent greenhouse gases.

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What is the common misconception regarding the weight of CFC molecules and their ability to reach the stratosphere?

Answer: CFC molecules are heavier than air and thus cannot ascend to the stratosphere.

Explanation: A common misconception is that CFC molecules, being heavier than air, cannot reach the stratosphere; however, atmospheric mixing allows them to ascend and participate in stratospheric chemical reactions.

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What policy action was taken regarding methyl bromide (MeBr) due to its ozone-depleting properties?

Answer: Its production and use were phased out under the Montreal Protocol.

Explanation: Methyl bromide (MeBr), recognized for its ozone-depleting potential, was subsequently controlled and phased out under the regulations of the Montreal Protocol.

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Why are chlorine and bromine atoms more damaging to ozone than fluorine atoms?

Answer: Both B and C are correct.

Explanation: Chlorine and bromine are more damaging because they persist as reactive catalysts longer, whereas fluorine atoms quickly form stable compounds like HF, terminating their catalytic cycles.

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Ozone Depletion Mechanisms

Once in the stratosphere, Ozone Depleting Substances (ODS) are immediately destroyed by UV radiation, preventing them from affecting ozone.

Answer: False

Explanation: ODS are transported to the stratosphere where UV radiation breaks them down, releasing halogen atoms that catalytically destroy ozone molecules over extended periods.

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A single chlorine atom can destroy approximately 100,000 ozone molecules before being removed from the stratosphere.

Answer: True

Explanation: Due to its catalytic nature, a single chlorine atom can destroy a vast number of ozone molecules, estimated at around 100,000, before being deactivated.

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Reservoir species like HCl and ClONO2 actively participate in the catalytic destruction of ozone.

Answer: False

Explanation: Reservoir species like HCl and ClONO2 temporarily store reactive chlorine, removing it from the catalytic cycle until conditions allow for its release.

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Polar stratospheric clouds (PSCs) facilitate ozone depletion by providing surfaces for reactions that convert inactive chlorine into reactive forms.

Answer: True

Explanation: PSCs play a critical role in polar ozone depletion by providing surfaces for chemical reactions that activate chlorine reservoirs, leading to rapid ozone destruction when sunlight returns.

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Arctic ozone depletion is generally less severe and more variable year-to-year compared to the Antarctic.

Answer: True

Explanation: Arctic ozone depletion exhibits greater year-to-year variability and is generally less severe than the consistent and pronounced depletion observed in the Antarctic ozone hole.

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The ozone hole forms over Antarctica mainly due to extreme cold temperatures that facilitate chemical reactions.

Answer: True

Explanation: The formation of the Antarctic ozone hole is primarily driven by extremely low winter temperatures that enable the formation of polar stratospheric clouds (PSCs), which are crucial for activating ozone-destroying chemicals.

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The polar vortex isolates cold air and PSCs over Antarctica, contributing to severe ozone depletion.

Answer: True

Explanation: The polar vortex acts as a containment system, trapping the cold air and PSCs necessary for severe ozone depletion within the Antarctic region during winter and spring.

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How does wildfire smoke contribute to ozone depletion?

Answer: By absorbing HCl, which facilitates the release of chlorine radicals that destroy ozone.

Explanation: Wildfire smoke particles can absorb hydrogen chloride (HCl), a process that facilitates the release of chlorine radicals, thereby contributing to ozone depletion.

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What role does the polar vortex play in the Antarctic ozone hole?

Answer: It traps cold air and PSCs, isolating the region for severe ozone depletion.

Explanation: The polar vortex isolates the extremely cold air masses over Antarctica, creating the necessary conditions for polar stratospheric cloud formation and subsequent catalytic ozone destruction.

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How does wildfire smoke contribute to ozone depletion?

Answer: By absorbing HCl, which facilitates the release of chlorine radicals that destroy ozone.

Explanation: Wildfire smoke particles can absorb hydrogen chloride (HCl), a process that facilitates the release of chlorine radicals, thereby contributing to ozone depletion.

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Impacts of Ozone Depletion

Increased levels of UVB ultraviolet light reaching the surface due to ozone depletion can lead to a higher incidence of skin cancer.

Answer: True

Explanation: Higher surface levels of UVB radiation resulting from ozone depletion are linked to increased risks of skin cancer, cataracts, and other health issues.

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Stratospheric ozone depletion leads to cooling of the stratosphere.

Answer: True

Explanation: Reduced ozone concentration in the stratosphere leads to less absorption of UV radiation, which is a primary heat source for this layer, resulting in stratospheric cooling.

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A one percent decrease in stratospheric ozone is estimated to increase basal and squamous cell carcinomas by approximately 2%.

Answer: True

Explanation: Estimates suggest that a sustained 1% reduction in stratospheric ozone leads to approximately a 2% increase in the incidence of basal and squamous cell carcinomas.

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Increased UVB radiation can negatively affect plants by reducing their photosynthesis rates.

Answer: True

Explanation: Elevated UVB radiation levels can impair plant physiology, leading to decreased photosynthesis rates and potentially affecting overall biomass and productivity.

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Substantial ozone depletion has been shown to reduce terrestrial plant productivity and carbon sequestration by up to 6%.

Answer: True

Explanation: Research indicates that areas experiencing significant ozone depletion may see reductions in terrestrial plant productivity and carbon sequestration by as much as 6% due to increased UV-B radiation.

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The greenhouse effect causes the stratosphere to cool.

Answer: Greenhouse gases trap heat in the troposphere, reducing heat transfer to the stratosphere.

Explanation: The greenhouse effect primarily warms the troposphere, which in turn reduces the amount of heat reaching the stratosphere, leading to stratospheric cooling.

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What is the estimated radiative forcing impact of observed stratospheric ozone losses?

Answer: A negative forcing of -0.15 W/m² contributing to cooling.

Explanation: Observed stratospheric ozone depletion has resulted in a negative radiative forcing, estimated around -0.15 W/m², which exerts a cooling influence on the Earth's surface and lower atmosphere.

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What is the estimated impact of substantial ozone depletion on terrestrial plant productivity?

Answer: A 6% decrease

Explanation: Studies indicate that substantial ozone depletion can lead to a reduction in terrestrial plant productivity and carbon sequestration by approximately 6% due to increased UV-B radiation.

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What is the scientific basis for the prediction that the stratosphere will cool due to the greenhouse effect?

Answer: Greenhouse gases trap heat in the troposphere, reducing heat transfer to the stratosphere.

Explanation: The greenhouse effect traps heat in the lower atmosphere (troposphere), thereby reducing the amount of heat available to warm the stratosphere, leading to its predicted cooling.

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What is the estimated radiative forcing impact of observed stratospheric ozone losses?

Answer: A negative forcing of -0.15 W/m² contributing to cooling.

Explanation: Observed stratospheric ozone depletion has resulted in a negative radiative forcing, estimated around -0.15 W/m², which exerts a cooling influence on the Earth's surface and lower atmosphere.

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What is the health impact of increased tropospheric ozone?

Answer: It is considered a health risk, particularly for vulnerable populations.

Explanation: Increased tropospheric ozone, or ground-level ozone, acts as a respiratory irritant and poses health risks, especially to children, the elderly, and individuals with pre-existing respiratory conditions.

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What potential benefit might increased UVB exposure offer?

Answer: Increased Vitamin D production in individuals deficient in it.

Explanation: Increased exposure to UVB radiation can stimulate the skin's production of Vitamin D, which is beneficial for individuals with existing Vitamin D deficiencies.

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Key Discoveries and Policy

The Montreal Protocol, signed in 1987, was the primary international agreement focused on phasing out CFCs.

Answer: True

Explanation: The Montreal Protocol is the landmark international treaty designed to phase out the production and consumption of ozone-depleting substances, including CFCs.

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The Montreal Protocol's success is attributed to its ability to phase out harmful chemicals like CFCs.

Answer: True

Explanation: The Montreal Protocol is widely recognized as a highly successful international agreement due to its effective implementation of phase-out schedules for ozone-depleting substances.

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The Antarctic ozone hole was first reported in 1985, showing reductions of up to 70% in the ozone column.

Answer: True

Explanation: The discovery and reporting of the Antarctic ozone hole in 1985 revealed dramatic springtime ozone reductions, initially up to 70%.

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Satellites initially failed to detect the ozone hole because their data quality control algorithms filtered out the depletion as errors.

Answer: True

Explanation: Initial satellite data indicating severe ozone depletion over Antarctica was disregarded as erroneous by automated quality control systems, delaying its recognition until ground-based data confirmed the phenomenon.

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The Montreal Protocol indirectly aids climate change mitigation by phasing out potent greenhouse gases.

Answer: True

Explanation: By phasing out ozone-depleting substances that are also potent greenhouse gases, the Montreal Protocol has made a significant indirect contribution to mitigating climate change.

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The discovery of the Antarctic ozone hole in 1985 had a significant impact on public awareness regarding ozone depletion.

Answer: True

Explanation: The revelation of the Antarctic ozone hole in 1985 dramatically increased public and political awareness, driving international efforts to address ozone depletion.

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World Ozone Day, September 16th, commemorates the signing of the Montreal Protocol.

Answer: True

Explanation: September 16th is designated as the International Day for the Preservation of the Ozone Layer to commemorate the signing of the Montreal Protocol in 1987.

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How did the 1985 discovery of the Antarctic ozone hole influence policy?

Answer: It galvanized international support for regulations like the Montreal Protocol.

Explanation: The scientific confirmation of the ozone hole provided compelling evidence that spurred global consensus and led to the adoption of international agreements like the Montreal Protocol.

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Why is September 16th designated as the International Day for the Preservation of the Ozone Layer?

Answer: It commemorates the signing of the Montreal Protocol.

Explanation: September 16th marks the anniversary of the signing of the Montreal Protocol in 1987, an event recognized globally through the International Day for the Preservation of the Ozone Layer.

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What was the scientific community's reaction to the 1985 discovery of the Antarctic ozone hole?

Answer: Shock, as it indicated significant damage from human-made chemicals.

Explanation: The discovery of the Antarctic ozone hole caused significant shock within the scientific community, as it demonstrated the profound impact of human-made chemicals on the global ozone layer.

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Ozone Layer Recovery

Antarctic ozone depletion levels have consistently remained below 20% reduction since the 1990s.

Answer: False

Explanation: Since the 1990s, Antarctic total column ozone has consistently been 40-50% lower than pre-ozone-hole levels during spring, indicating significant depletion.

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The ozone layer is projected to fully recover to pre-1980 levels around the year 2075.

Answer: True

Explanation: Current projections, based on the Montreal Protocol's effectiveness, estimate the ozone layer will recover to pre-1980 levels around 2075, although specific regional recoveries may vary.

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Very Short-Lived Substances (VSLS) are strictly regulated by the Montreal Protocol due to their significant ozone-depleting potential.

Answer: False

Explanation: The Montreal Protocol does not strictly regulate VSLS, as they are not expected to reach the stratosphere in quantities sufficient to cause substantial ozone depletion, although some man-made VSLS are of concern.

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The Arctic ozone layer is projected to recover around 2040, earlier than the Antarctic.

Answer: True

Explanation: Projections indicate that the Arctic ozone layer is expected to recover to 1980 levels around 2040, preceding the projected recovery timeline for the Antarctic region.

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What is the projected recovery timeline for the ozone layer over the Arctic region?

Answer: Around 2040

Explanation: The Arctic ozone layer is projected to recover to 1980 levels by approximately 2040, according to current scientific assessments.

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What does the 2019 report of the ozone hole being the smallest in decades signify?

Answer: Positive progress in the ozone layer's recovery.

Explanation: The observation of a significantly smaller ozone hole in 2019 was interpreted as a positive indicator of the ozone layer's gradual recovery, attributed to the success of the Montreal Protocol.

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According to a 2023 UN assessment, when is the ozone layer projected to recover over Antarctica?

Answer: 2066

Explanation: A 2023 UN assessment projects that the ozone layer over Antarctica is expected to recover to 1980 levels by approximately 2066.

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