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Preserving Legacies

An in-depth exploration into the chemical processes and preservation strategies safeguarding our written heritage from "slow fires" and acidic degradation.

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What is Mass Deacidification?

The "Slow Fires" Threat

Mass deacidification is a critical intervention in library and information science, designed to combat the pervasive degradation of paper in older books, often termed "slow fires." This phenomenon, prevalent in books produced after the 1850s, stems from the widespread use of cheaper, simpler acidic paper manufacturing methods. Over time, especially when exposed to light, air pollution, or high humidity, this paper yellows and becomes increasingly brittle.[1]

The Chemical Solution

The fundamental goal of mass deacidification is to elevate the pH of acidic paper, thereby neutralizing existing acids and depositing an alkaline agent. This alkaline reserve acts as a buffer, preventing further decay and extending the lifespan of invaluable documents and books.[2] This process is specifically targeted at acidic paper objects that face irreversible loss without intervention.

A Race Against Time

The urgency of mass deacidification is underscored by historical research. William J. Barrow's studies revealed that a staggering proportionโ€”no more than three percentโ€”of books published between 1900 and 1949 would survive beyond fifty years due to acid degradation. This alarming prognosis spurred the formation of the Association of Research Libraries' Standing Committee on the Preservation of Research Library Materials in 1960, highlighting the long-standing recognition of this preservation challenge.[4]

History & Evolution

Early Research & Hydrolysis

The development of mass deacidification, alongside techniques like microfilm and lamination, emerged in the early to mid-20th century as a direct response to the chemical process of hydrolysis. Hydrolysis breaks down the fibers that give paper its structural integrity, leading to increasing brittleness. Environmental pollutants exacerbate this by reacting with paper to form acids, which in turn promote oxidation and create more acid, initiating a destructive autocatalytic feedback loop.[3]

Barrow's Aqueous Method

William J. Barrow pioneered an aqueous process designed to neutralize acid within paper. This method simultaneously deposited an alkaline buffer, effectively slowing the rate of decay. His foundational work laid the groundwork for subsequent research into more efficient and scalable deacidification techniques.[5]

Non-Aqueous & Vaporous Approaches

Following Barrow's initial success, researchers explored alternative methods to reduce the time, labor, and cost associated with deacidification. These included non-aqueous processes utilizing organic solvents and vaporous treatments, such as the Library of Congress's Diethylzinc (DEZ) method. The aim was to achieve the same preservation results through different chemical pathways.[6]

The DEZ Debacle

A Volatile Experiment

The diethylzinc (DEZ) treatment, a vaporous method, was theoretically promising. It proposed placing books in an evacuated chamber, introducing DEZ to react with acidic residues, and leaving an alkaline buffer.[7] However, practical application proved disastrous. The heating required to remove trace water from books (DEZ reacts violently with water) accelerated paper degradation. Furthermore, DEZ reacted with other book components like glues and bindings, causing additional damage and producing unpleasant odors.[8]

In the 1980s, NASA constructed a pilot plant for mass deacidification using the DEZ process, testing it with books from the Library of Congress. A critical incident occurred in 1986 when DEZ was not fully removed in one run, pooling at the bottom of the chamber. Given DEZ's violent flammability upon contact with oxygen or water vapor, the chamber could not be safely opened. Ultimately, explosives were used to rupture the suspect plumbing, confirming the presence of residual DEZ through a subsequent fire that destroyed the plant. This significant failure is extensively documented by Nicholson Baker in his book Double Fold.

Subsequent attempts by the chemical company AkzoNobel to refine the DEZ process managed to reduce the risks of fire and explosions through improved design. However, issues of damage to books and persistent odors remained problematic. Ultimately, AkzoNobel concluded that the process was not commercially viable and ceased its research at the end of 1994.

Ideal Outcomes

pH Balance & Distribution

An ideal mass deacidification treatment, as envisioned by the Library of Congress in 1994, must effectively neutralize acidic paper and introduce an alkaline reserve. Crucially, it should achieve a pH value between 6.8 and 10.4, ensuring this alkaline state is uniformly distributed throughout the entire book.[9]

Material Integrity

Beyond chemical efficacy, the process must be benign to the physical components of the book. This means it should not inflict any damage upon adhesives, inks, or dyes. Furthermore, it should not induce any undesirable odors or alter the original color of the paper, preserving the aesthetic and sensory qualities of the artifact.[9]

Structural & Chemical Safety

Maintaining the mechanical integrity of the paper is paramount; there should be no loss of pliancy or mechanical strength. Faculty members from the Slovak University of Technology further emphasized that the chemicals employed must be safe for both the materials and operators, the process should be universally applicable to any type of paper, and it must not cause swelling or warping of the paper.[9][10]

Practical Effects

pH Achievement

Studies conducted by the European Commission on Preservation and Access, the Library of Congress, and the Centre de Recherches sur la Conservation des Documents Graphiques in the 1990s confirmed that all evaluated processes successfully imparted an adequately high pH. For instance, BookKeeper achieved a pH of 9โ€“10,[9] CSC Book Saver yielded 8.78โ€“10.5,[11] Wei T'o ranged from 7.5 to 10.4,[12] and Papersave produced a pH of 7.5โ€“9.[13]

Unintended Cosmetic Changes

Despite achieving the desired pH, these studies also revealed various adverse cosmetic side effects across different processes:

  • BookKeeper: Left a "palpable residue," caused clamp marks on covers, and some colored inks to rub off.[9]
  • CSC Book Saver: Resulted in a "white powdery deposit" on books.[14]
  • Papersave: Led to "discoloration, white deposit, Newton's rings, bleeding of inks and dyes, odor and different 'feel' of the paper."[15]
  • Wei T'o: Caused "odor, white residues, rings, cockling, (yellow) discolorations and adhesive bleeding."[16]

Conservators at the British Library acknowledge that existing mass deacidification processes are still under development, necessitating further research into their long-term chemical and mechanical effects.[17]

Commercial Solutions

BookKeeper Process

The BookKeeper process is a non-aqueous, liquid-phase method that employs magnesium oxide as its active alkaline agent.[18] This service is globally available through Preservation Technologies, L.P., with operational plants in the U.S., Spain, Japan, Poland, The Netherlands, South Africa, and Qatar. Additionally, Fratielivi in Italy also offers the BookKeeper process.[19]

CSC Book Saver

The CSC Book Saver utilizes carbonated magnesium propylate for its deacidification treatment.[20] This process is primarily accessible in Europe through Conservaciรณn de Sustratos Celulรณsicos S.L. (CSC), based in Barcelona, Spain.[21]

Papersave Process

Developed by Battelle Ingenieurtechnik GmbH, the Papersave process, sometimes referred to as "the Battelle Process," uses magnesium titanium alkoxide.[20] In Europe, this service is provided by Nitrochemie Wimmis (known as Papersave Swiss) in Switzerland and the Zentrum fรผr Bucherhaltung in Leipzig, Germany.[22][23]

Wei T'o Process

The Wei T'o process utilizes methoxy magnesium methyl carbonate or isopropoxy magnesium isopropyl carbonate.[16] While new products were anticipated in 2008, Wei T'o is more commonly applied for single-item deacidification rather than mass treatment. Wei T'o products are available through Wei T'o Associates Inc. in Matteson, U.S.[24] All these commercial solutions are also available in convenient hand-held spray formats for localized application.

Adoption & Economics

Library vs. Archive Adoption

While prominent research libraries, such as the Library of Congress and the New York Public Library, have embraced deacidification, its adoption by archives, particularly in the United States, has been less widespread. European national archives have experimented with these techniques, but the U.S. National Archives and Records Administration (NARA), despite pioneering an improved aqueous technique, opted to allocate its preservation funds to other areas.[5]

In 2000, NARA's Chief of the Document Conservation Laboratory articulated several reasons for not implementing a mass deacidification program. These included the observation that many papers entering NARA's collections were of higher quality than typical library materials. Furthermore, records from federal agencies are not transferred to NARA until they are at least 30 years old, by which point acidic paper would have already suffered irreversible weakening. Given limited resources, NARA prioritized other preservation efforts, such as climate control, aiming for the "maximum benefit for the greatest number of records" under its Twenty-Year Preservation Plan.[25]

Interestingly, studies by the Harry Ransom Humanities Research Center and the General State Archive of the Netherlands suggested that the DEZ method, despite its historical failures, might be particularly suitable for archival materials.[26]

Cost Considerations

Estimates from the early 1990s placed deacidification costs, excluding transportation and handling, at $5โ€“10 per volume.[27] Between 1995 and 1997, the Library of Congress, with a $2 million appropriation, deacidified 72,000 books using the BookKeeper method at an actual cost of $11.70 per book.[28]

A 2003 cost comparison with reformatting options highlighted the economic viability of deacidification: microfilming cost $125 per volume, scanning with minimal indexing was $50, while a New York Public Library project showed deacidification at $16.20 per volume.[6] However, by 2004, Google Books was able to scan books for a competitive $10โ€“20 each.[29] As of 2022, there are five mass deacidification plants operating worldwide.[30]

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References

References

  1.  Cheradame, H et al. (2003). Mass Deacidification of paper and books: I: study of the limitations of the gas phase process. Restaurator: International Journal for the Preservation of Library and Archival Material, 24, 227.
  2.  Lienardy, A. & Van Damme, P. (1990). Practical Deacidification, Restaurator: International Journal for the Preservation of Library and Archival Material, 11,2.
  3.  Library of Congress. (1994). An evaluation of the BookKeeper mass deacidification process: Technical Evaluation Team Report for the Preservation Directorate, Library of Congress, Appendix E.
  4.  Cedzova, M. et al. (2006). Patents for Paper Deacidification. Restaurator: International Journal for the Preservation of Library and Archival Material,27, 36.
  5.  Dupont, A. et al. (2002). Testing CSC Book Saver, a commercial deacidification process. Restaurator: International Journal for the Preservation of Library and Archival Material,23, 40.
  6.  Wittekind, J. (1994). The Battelle mass deacidification process: A New method for deacidifying books and archival materials. Restaurator: International Journal for the Preservation of Library and Archival Material,15, 195.
  7.  Dupont, A. et al. (2002). Testing CSC Book Saver, a commercial deacidification process. Restaurator: International Journal for the Preservation of Library and Archival Material,23, 45.
  8.  Banik, G. (2003). Mass deacidification technology in Germany and its Quality Control. Restaurator: International Journal for the Preservation of Library and Archival Material,26, 64.
A full list of references for this article are available at the Mass deacidification Wikipedia page

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Important Notice

This page was generated by an Artificial Intelligence and is intended for informational and educational purposes only. The content is based on a snapshot of publicly available data from Wikipedia and may not be entirely accurate, complete, or up-to-date.

This is not professional preservation, chemical, or archival advice. The information provided on this website is not a substitute for professional consultation with qualified conservators, chemists, or archival specialists. Always refer to official guidelines and consult with experts for specific preservation needs. Never disregard professional advice because of something you have read on this website.

The creators of this page are not responsible for any errors or omissions, or for any actions taken based on the information provided herein.