Preserving Legacies
An in-depth exploration into the chemical processes and preservation strategies safeguarding our written heritage from "slow fires" and acidic degradation.
What is it? ๐ Explore Methods ๐งชDive in with Flashcard Learning!
๐ฎ Play the Wiki2Web Clarity Challenge Game๐ฎ
What is Mass Deacidification?
The "Slow Fires" Threat
Mass deacidification is a critical intervention in library and information science, designed to combat the pervasive degradation of paper in older books, often termed "slow fires." This phenomenon, prevalent in books produced after the 1850s, stems from the widespread use of cheaper, simpler acidic paper manufacturing methods. Over time, especially when exposed to light, air pollution, or high humidity, this paper yellows and becomes increasingly brittle.[1]
The Chemical Solution
The fundamental goal of mass deacidification is to elevate the pH of acidic paper, thereby neutralizing existing acids and depositing an alkaline agent. This alkaline reserve acts as a buffer, preventing further decay and extending the lifespan of invaluable documents and books.[2] This process is specifically targeted at acidic paper objects that face irreversible loss without intervention.
A Race Against Time
The urgency of mass deacidification is underscored by historical research. William J. Barrow's studies revealed that a staggering proportionโno more than three percentโof books published between 1900 and 1949 would survive beyond fifty years due to acid degradation. This alarming prognosis spurred the formation of the Association of Research Libraries' Standing Committee on the Preservation of Research Library Materials in 1960, highlighting the long-standing recognition of this preservation challenge.[4]
History & Evolution
Early Research & Hydrolysis
The development of mass deacidification, alongside techniques like microfilm and lamination, emerged in the early to mid-20th century as a direct response to the chemical process of hydrolysis. Hydrolysis breaks down the fibers that give paper its structural integrity, leading to increasing brittleness. Environmental pollutants exacerbate this by reacting with paper to form acids, which in turn promote oxidation and create more acid, initiating a destructive autocatalytic feedback loop.[3]
Barrow's Aqueous Method
William J. Barrow pioneered an aqueous process designed to neutralize acid within paper. This method simultaneously deposited an alkaline buffer, effectively slowing the rate of decay. His foundational work laid the groundwork for subsequent research into more efficient and scalable deacidification techniques.[5]
Non-Aqueous & Vaporous Approaches
Following Barrow's initial success, researchers explored alternative methods to reduce the time, labor, and cost associated with deacidification. These included non-aqueous processes utilizing organic solvents and vaporous treatments, such as the Library of Congress's Diethylzinc (DEZ) method. The aim was to achieve the same preservation results through different chemical pathways.[6]
The DEZ Debacle
A Volatile Experiment
The diethylzinc (DEZ) treatment, a vaporous method, was theoretically promising. It proposed placing books in an evacuated chamber, introducing DEZ to react with acidic residues, and leaving an alkaline buffer.[7] However, practical application proved disastrous. The heating required to remove trace water from books (DEZ reacts violently with water) accelerated paper degradation. Furthermore, DEZ reacted with other book components like glues and bindings, causing additional damage and producing unpleasant odors.[8]
Ideal Outcomes
pH Balance & Distribution
An ideal mass deacidification treatment, as envisioned by the Library of Congress in 1994, must effectively neutralize acidic paper and introduce an alkaline reserve. Crucially, it should achieve a pH value between 6.8 and 10.4, ensuring this alkaline state is uniformly distributed throughout the entire book.[9]
Material Integrity
Beyond chemical efficacy, the process must be benign to the physical components of the book. This means it should not inflict any damage upon adhesives, inks, or dyes. Furthermore, it should not induce any undesirable odors or alter the original color of the paper, preserving the aesthetic and sensory qualities of the artifact.[9]
Structural & Chemical Safety
Maintaining the mechanical integrity of the paper is paramount; there should be no loss of pliancy or mechanical strength. Faculty members from the Slovak University of Technology further emphasized that the chemicals employed must be safe for both the materials and operators, the process should be universally applicable to any type of paper, and it must not cause swelling or warping of the paper.[9][10]
Practical Effects
pH Achievement
Studies conducted by the European Commission on Preservation and Access, the Library of Congress, and the Centre de Recherches sur la Conservation des Documents Graphiques in the 1990s confirmed that all evaluated processes successfully imparted an adequately high pH. For instance, BookKeeper achieved a pH of 9โ10,[9] CSC Book Saver yielded 8.78โ10.5,[11] Wei T'o ranged from 7.5 to 10.4,[12] and Papersave produced a pH of 7.5โ9.[13]
Unintended Cosmetic Changes
Despite achieving the desired pH, these studies also revealed various adverse cosmetic side effects across different processes:
- BookKeeper: Left a "palpable residue," caused clamp marks on covers, and some colored inks to rub off.[9]
- CSC Book Saver: Resulted in a "white powdery deposit" on books.[14]
- Papersave: Led to "discoloration, white deposit, Newton's rings, bleeding of inks and dyes, odor and different 'feel' of the paper."[15]
- Wei T'o: Caused "odor, white residues, rings, cockling, (yellow) discolorations and adhesive bleeding."[16]
Conservators at the British Library acknowledge that existing mass deacidification processes are still under development, necessitating further research into their long-term chemical and mechanical effects.[17]
Commercial Solutions
BookKeeper Process
The BookKeeper process is a non-aqueous, liquid-phase method that employs magnesium oxide as its active alkaline agent.[18] This service is globally available through Preservation Technologies, L.P., with operational plants in the U.S., Spain, Japan, Poland, The Netherlands, South Africa, and Qatar. Additionally, Fratielivi in Italy also offers the BookKeeper process.[19]
CSC Book Saver
The CSC Book Saver utilizes carbonated magnesium propylate for its deacidification treatment.[20] This process is primarily accessible in Europe through Conservaciรณn de Sustratos Celulรณsicos S.L. (CSC), based in Barcelona, Spain.[21]
Papersave Process
Developed by Battelle Ingenieurtechnik GmbH, the Papersave process, sometimes referred to as "the Battelle Process," uses magnesium titanium alkoxide.[20] In Europe, this service is provided by Nitrochemie Wimmis (known as Papersave Swiss) in Switzerland and the Zentrum fรผr Bucherhaltung in Leipzig, Germany.[22][23]
Wei T'o Process
The Wei T'o process utilizes methoxy magnesium methyl carbonate or isopropoxy magnesium isopropyl carbonate.[16] While new products were anticipated in 2008, Wei T'o is more commonly applied for single-item deacidification rather than mass treatment. Wei T'o products are available through Wei T'o Associates Inc. in Matteson, U.S.[24] All these commercial solutions are also available in convenient hand-held spray formats for localized application.
Adoption & Economics
Library vs. Archive Adoption
While prominent research libraries, such as the Library of Congress and the New York Public Library, have embraced deacidification, its adoption by archives, particularly in the United States, has been less widespread. European national archives have experimented with these techniques, but the U.S. National Archives and Records Administration (NARA), despite pioneering an improved aqueous technique, opted to allocate its preservation funds to other areas.[5]
Cost Considerations
Estimates from the early 1990s placed deacidification costs, excluding transportation and handling, at $5โ10 per volume.[27] Between 1995 and 1997, the Library of Congress, with a $2 million appropriation, deacidified 72,000 books using the BookKeeper method at an actual cost of $11.70 per book.[28]
A 2003 cost comparison with reformatting options highlighted the economic viability of deacidification: microfilming cost $125 per volume, scanning with minimal indexing was $50, while a New York Public Library project showed deacidification at $16.20 per volume.[6] However, by 2004, Google Books was able to scan books for a competitive $10โ20 each.[29] As of 2022, there are five mass deacidification plants operating worldwide.[30]
Teacher's Corner
Edit and Print this course in the Wiki2Web Teacher Studio

Click here to open the "Mass Deacidification" Wiki2Web Studio curriculum kit
Use the free Wiki2web Studio to generate printable flashcards, worksheets, exams, and export your materials as a web page or an interactive game.
True or False?
Test Your Knowledge!
Gamer's Corner
Are you ready for the Wiki2Web Clarity Challenge?

Unlock the mystery image and prove your knowledge by earning trophies. This simple game is addictively fun and is a great way to learn!
Play now
References
References
- Cheradame, H et al. (2003). Mass Deacidification of paper and books: I: study of the limitations of the gas phase process. Restaurator: International Journal for the Preservation of Library and Archival Material, 24, 227.
- Lienardy, A. & Van Damme, P. (1990). Practical Deacidification, Restaurator: International Journal for the Preservation of Library and Archival Material, 11,2.
- Library of Congress. (1994). An evaluation of the BookKeeper mass deacidification process: Technical Evaluation Team Report for the Preservation Directorate, Library of Congress, Appendix E.
- Cedzova, M. et al. (2006). Patents for Paper Deacidification. Restaurator: International Journal for the Preservation of Library and Archival Material,27, 36.
- Dupont, A. et al. (2002). Testing CSC Book Saver, a commercial deacidification process. Restaurator: International Journal for the Preservation of Library and Archival Material,23, 40.
- Wittekind, J. (1994). The Battelle mass deacidification process: A New method for deacidifying books and archival materials. Restaurator: International Journal for the Preservation of Library and Archival Material,15, 195.
- Dupont, A. et al. (2002). Testing CSC Book Saver, a commercial deacidification process. Restaurator: International Journal for the Preservation of Library and Archival Material,23, 45.
- Banik, G. (2003). Mass deacidification technology in Germany and its Quality Control. Restaurator: International Journal for the Preservation of Library and Archival Material,26, 64.
Feedback & Support
To report an issue with this page, or to find out ways to support the mission, please click here.
Disclaimer
Important Notice
This page was generated by an Artificial Intelligence and is intended for informational and educational purposes only. The content is based on a snapshot of publicly available data from Wikipedia and may not be entirely accurate, complete, or up-to-date.
This is not professional preservation, chemical, or archival advice. The information provided on this website is not a substitute for professional consultation with qualified conservators, chemists, or archival specialists. Always refer to official guidelines and consult with experts for specific preservation needs. Never disregard professional advice because of something you have read on this website.
The creators of this page are not responsible for any errors or omissions, or for any actions taken based on the information provided herein.