The Salinity Spectrum
An academic exploration of salinity's definition, measurement, and profound environmental implications.
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Definitions
Conceptual Understanding
Salinity refers to the measure of dissolved salts within a body of water, commonly termed saline water. It is typically quantified in grams per liter (g/L) or grams per kilogram (g/kg), with the latter serving as a dimensionless value equivalent to parts per thousand (โฐ). This parameter is fundamental to understanding the chemical properties of natural waters and influences biological processes within them. Furthermore, salinity acts as a thermodynamic state variable, which, alongside temperature and pressure, dictates crucial physical characteristics such as water density and heat capacity, thereby impacting ocean currents and atmospheric heat exchange.
Operational Measurement
While conceptually straightforward, the precise definition and measurement of salinity present technical challenges. Operationally, dissolved matter is defined as that which can pass through a fine filter, historically 0.45 ฮผm, but more recently 0.2 ฮผm. Salinity can be expressed as a mass fractionโthe mass of dissolved material relative to the total mass of the solution. Seawater typically exhibits a mass salinity of approximately 35 g/kg, though values near coastal riverine inputs are often lower. Freshwater bodies display a wide range, from less than 0.01 g/kg to several g/kg, with exceptions like the Dead Sea exceeding 200 g/kg.
Precision in Oceanography
For physical oceanographers, particularly those studying the abyssal ocean, achieving high precision and inter-comparability in salinity measurements is paramount, often requiring accuracy to five significant digits. To meet these stringent requirements, oceanographers utilize standardized reference materials like the International Association for the Physical Sciences of the Oceans (IAPSO) standard seawater. This ensures consistency across different researchers and measurement periods.
Composition
Elemental and Molecular Forms
Natural waters contain a complex mixture of dissolved substances originating from various sources, not all of which are simple salts. These substances exist in different molecular and ionic forms, whose chemical properties can be influenced by temperature and pressure. Measuring these constituents with high accuracy and performing complete chemical analyses for every sample is often impractical.
Major and Minor Ions
For practical purposes, salinity is often related to the sum of masses of a specific subset of dissolved chemical constituents, referred to as 'solution salinity'. In most natural waters, the inorganic composition is dominated by eight major ions. For seawater analyses requiring the highest precision, seven minor ions are also included. While these ions constitute the bulk of dissolved matter, exceptions exist in certain environments like pit lakes or hydrothermal springs.
Gases and Other Dissolved Matter
Dissolved gases such as oxygen and nitrogen are typically not included in salinity calculations. However, carbon dioxide, which dissolves and partially converts into carbonates and bicarbonates, is often considered. Silicon, present as silicic acid, may also be included in salinity/density relationship studies, particularly within the typical pH range of natural waters.
Seawater Salinity
Historical Measurement Techniques
Historically, salinity in seawater was primarily determined using titration methods. Titration with silver nitrate allowed for the quantification of halide ions (chlorine and bromine), yielding a value known as chlorinity. This chlorinity value was then multiplied by a conversion factor to estimate the total salt content, resulting in 'Knudsen salinities' expressed in parts per thousand (ppt or โฐ).
Practical Salinity Scale (PSS-78)
The advent of electrical conductivity measurements led to the development of the Practical Salinity Scale 1978 (PSS-78). This scale relates salinity to the electrical conductivity of seawater. Salinities measured using PSS-78 are technically dimensionless, though the suffix 'psu' or 'PSU' (practical salinity unit) is sometimes appended. However, the formal addition of 'PSU' as a unit is discouraged.
TEOS-10 Standard
Introduced in 2010, the International Thermodynamic Equation of Seawater 2010 (TEOS-10) represents a significant advancement. It advocates for 'Absolute Salinity' as a replacement for practical salinity and introduces 'Conservative Temperature'. Absolute salinity is expressed as a mass fraction (g/kg) and is determined by combining conductivity measurements with additional data that accounts for regional variations in seawater composition, or through direct density measurements. A typical seawater sample with a chlorinity of 19.37 โฐ corresponds to a Knudsen salinity of 35.00 โฐ, a PSS-78 practical salinity of approximately 35.0, and a TEOS-10 absolute salinity of about 35.2 g/kg.
Lakes and Rivers
Freshwater Definitions
In limnology and chemistry, salinity is often defined by the mass of salt per unit volume, typically expressed in milligrams per liter (mg/L) or grams per liter (g/L). This value is generally accurate at a reference temperature, as solution volume varies with temperature. These measurements usually have an accuracy of about 1%.
Conductivity as a Proxy
Limnologists frequently employ electrical conductivity (EC) as a proxy for salinity, often referred to as 'reference conductivity'. This measurement can be corrected for temperature effects and is usually reported in units of ฮผS/cm. A river or lake water with a salinity of approximately 70 mg/L typically exhibits a specific conductivity between 80 and 130 ฮผS/cm at 25 ยฐC, though the exact ratio depends on the specific ions present. Conductivity typically changes by about 2% per degree Celsius.
Density Measurements
Direct density measurements are also utilized to estimate salinities, particularly in highly saline lakes. Sometimes, density at a specific temperature serves as a salinity proxy. In other cases, empirical salinity/density relationships, developed for a particular water body, are applied to estimate salinity from measured density values.
Classification
Salinity Levels
Water bodies are classified based on their salinity content, with distinct categories reflecting the concentration of dissolved salts:
Water Salinity | |||
---|---|---|---|
Fresh Water | Brackish Water | Saline Water | Brine |
< 0.05% | 0.05 โ 3% | 3 โ 5% | > 5% |
< 0.5 โฐ | 0.5 โ 30 โฐ | 30 โ 50 โฐ | > 50 โฐ |
Marine and Thalassic Waters
Marine waters, synonymous with euhaline seas, typically exhibit salinities ranging from 30 to 35 โฐ. Brackish seas or waters fall within the 0.5 to 29 โฐ range, while metahaline seas have salinities between 36 and 40 โฐ. These are considered thalassic, meaning their salinity originates from the ocean. Homoiohaline environments maintain relatively constant salinity over time.
Poikilohaline Variability
In contrast, poikilohaline environments are characterized by significant seasonal or temporal variations in salinity, which are biologically meaningful. These salinities can range widely, from 0.5 โฐ to over 300 โฐ. Highly saline water from which salts are crystallizing (or are about to) is specifically termed brine.
Environmental Considerations
Ecological Impact
Salinity is a critical ecological factor, profoundly influencing the types of organisms that can inhabit aquatic environments. It dictates the suitability of water for plant life, both within water bodies and on adjacent land irrigated by them. Plants adapted to saline conditions are known as halophytes, with specific types like glasswort and saltwort being tolerant of residual sodium carbonate salinity. Organisms capable of thriving in highly saline conditions are classified as extremophiles, specifically halophiles.
Water Use and Pollution
The removal of salts from water is an expensive process, making salinity a key consideration for water potability and suitability for irrigation. Increases in salinity have been observed in lakes and rivers, often attributed to the runoff of road salts and other de-icing agents. These increases can have significant impacts on freshwater ecosystems.
Ocean Circulation and Climate
Ocean salinity plays a pivotal role in driving global ocean circulation through the thermohaline circulation. Variations in salinity, along with temperature, alter water density, leading to the sinking and rising of water masses. Changes in ocean salinity are also linked to atmospheric carbon dioxide levels, as saltier waters exhibit lower solubility for CO2. Recent decades have seen complex changes in North Atlantic salinity, influenced by factors such as Greenland meltwater flux and shifts in ocean currents, highlighting the interconnectedness of climate and oceanographic processes.
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References
References
- World Ocean Atlas 2009. nodc.noaa.gov
- Unesco (1981). The Practical Salinity Scale 1978 and the International Equation of State of Seawater 1980. Tech. Pap. Mar. Sci., 36
- Unesco (1981). Background papers and supporting data on the Practical Salinity Scale 1978. Tech. Pap. Mar. Sci., 37
- Venice system (1959). The final resolution of the symposium on the classification of brackish waters. Archo Oceanogr. Limnol., 11 (suppl): 243รขยย248.
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Important Notice
This page has been generated by an Artificial Intelligence and is intended for informational and educational purposes exclusively. The content is derived from a snapshot of publicly available data and may not be entirely accurate, comprehensive, or current.
This is not professional scientific or environmental advice. The information provided herein is not a substitute for expert consultation in fields such as oceanography, environmental science, or water resource management. Always consult with qualified professionals for specific applications and refer to official scientific documentation for critical data.
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