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Crystallography: The Hexagonal Crystal Family and Related Structures

At a Glance

Title: Crystallography: The Hexagonal Crystal Family and Related Structures

Total Categories: 6

Category Stats

  • The Hexagonal Crystal Family: Definition and Scope: 7 flashcards, 8 questions
  • Hexagonal Crystal System: Symmetry, Systems, and Space Groups: 5 flashcards, 4 questions
  • Trigonal Crystal System: Symmetry, Systems, and Space Groups: 5 flashcards, 7 questions
  • Lattice Descriptions and Unit Cells: 12 flashcards, 10 questions
  • Specific Structures: Wurtzite and Nickel Arsenide: 18 flashcards, 20 questions
  • Mineral and Compound Examples: 3 flashcards, 7 questions

Total Stats

  • Total Flashcards: 50
  • True/False Questions: 26
  • Multiple Choice Questions: 30
  • Total Questions: 56

Instructions

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Study Guide: Crystallography: The Hexagonal Crystal Family and Related Structures

Study Guide: Crystallography: The Hexagonal Crystal Family and Related Structures

The Hexagonal Crystal Family: Definition and Scope

The hexagonal crystal family comprises two Bravais lattices: the hexagonal and the rhombohedral lattices.

Answer: True

The hexagonal crystal family is constituted by the hexagonal lattice system and the rhombohedral lattice system, each containing a single Bravais lattice.

Related Concepts:

  • What are the two lattice systems that constitute the hexagonal crystal family?: The hexagonal crystal family is composed of two lattice systems: the hexagonal lattice system and the rhombohedral lattice system. Each of these lattice systems contains a single Bravais lattice.
  • How does the hexagonal crystal family relate to the trigonal and hexagonal crystal systems?: The hexagonal crystal family is defined as the union of the trigonal crystal system and the hexagonal crystal system. It encompasses all point groups that have space groups assigned to either the hexagonal or the rhombohedral lattice system.

The hexagonal crystal family is associated with a total of 52 space groups.

Answer: True

The hexagonal crystal family encompasses precisely 52 space groups, corresponding to those assigned to either the hexagonal or rhombohedral lattice systems.

Related Concepts:

  • What is the total number of space groups associated with the hexagonal crystal family?: The hexagonal crystal family is associated with a total of 52 space groups. These are precisely the space groups whose underlying Bravais lattice is either hexagonal or rhombohedral.

Which two crystal systems are included within the hexagonal crystal family?

Answer: The hexagonal and trigonal crystal systems

The hexagonal crystal family is defined as the union of the hexagonal crystal system and the trigonal crystal system.

Related Concepts:

  • What is the hexagonal crystal family in crystallography?: In crystallography, the hexagonal crystal family is one of the six recognized crystal families. It is characterized by including two specific crystal systems: the hexagonal and the trigonal systems. Furthermore, it encompasses two lattice systems: the hexagonal and the rhombohedral lattice systems, representing all point groups whose space groups are based on the hexagonal lattice.
  • How does the hexagonal crystal family relate to the trigonal and hexagonal crystal systems?: The hexagonal crystal family is defined as the union of the trigonal crystal system and the hexagonal crystal system. It encompasses all point groups that have space groups assigned to either the hexagonal or the rhombohedral lattice system.

The hexagonal crystal family is composed of which two lattice systems?

Answer: Hexagonal and rhombohedral lattice systems

The hexagonal crystal family is constituted by the hexagonal lattice system and the rhombohedral lattice system.

Related Concepts:

  • What are the two lattice systems that constitute the hexagonal crystal family?: The hexagonal crystal family is composed of two lattice systems: the hexagonal lattice system and the rhombohedral lattice system. Each of these lattice systems contains a single Bravais lattice.

What is the total number of space groups associated with the hexagonal crystal family?

Answer: 52

The hexagonal crystal family is associated with a total of 52 space groups, which are precisely those assigned to either the hexagonal or rhombohedral lattice systems.

Related Concepts:

  • What is the total number of space groups associated with the hexagonal crystal family?: The hexagonal crystal family is associated with a total of 52 space groups. These are precisely the space groups whose underlying Bravais lattice is either hexagonal or rhombohedral.

What is the distinction between a crystal family and a crystal system?

Answer: A system groups point groups, a family groups crystal systems

A crystal system classifies based on point group symmetry and lattice assignment, while a crystal family groups crystal systems that share common lattice types and symmetry characteristics.

Related Concepts:

  • What is the distinction between a crystal family and a crystal system?: A crystal family is a classification that groups crystal systems based on shared lattice types and symmetry characteristics. A crystal system is a more specific classification based on the symmetry elements present in a point group and its assignment to a particular lattice system.

The hexagonal crystal family includes both the hexagonal and rhombohedral lattice systems.

Answer: True

The hexagonal crystal family is defined by its inclusion of both the hexagonal lattice system and the rhombohedral lattice system.

Related Concepts:

  • What are the two lattice systems that constitute the hexagonal crystal family?: The hexagonal crystal family is composed of two lattice systems: the hexagonal lattice system and the rhombohedral lattice system. Each of these lattice systems contains a single Bravais lattice.
  • How does the hexagonal crystal family relate to the trigonal and hexagonal crystal systems?: The hexagonal crystal family is defined as the union of the trigonal crystal system and the hexagonal crystal system. It encompasses all point groups that have space groups assigned to either the hexagonal or the rhombohedral lattice system.

The hexagonal crystal family encompasses crystal systems defined by specific rotational symmetry axes. Which statement accurately reflects this relationship?

Answer: The hexagonal crystal family contains systems characterized by both three-fold and six-fold axes of rotation.

The hexagonal crystal family is defined as the union of the trigonal crystal system (characterized by a three-fold axis of rotation) and the hexagonal crystal system (characterized by a six-fold axis of rotation).

Related Concepts:

  • How does the hexagonal crystal family relate to the trigonal and hexagonal crystal systems?: The hexagonal crystal family is defined as the union of the trigonal crystal system and the hexagonal crystal system. It encompasses all point groups that have space groups assigned to either the hexagonal or the rhombohedral lattice system.
  • What are the defining symmetry requirements for the hexagonal crystal system?: The hexagonal crystal system is characterized by point groups that possess at least one six-fold axis of rotation. This system comprises 7 distinct point groups.
  • What are the defining symmetry requirements for the trigonal crystal system?: The trigonal crystal system is defined by point groups that possess at least one three-fold axis of rotation. This system includes 5 distinct point groups.

Hexagonal Crystal System: Symmetry, Systems, and Space Groups

What symmetry element characterizes the hexagonal crystal system?

Answer: A six-fold axis of rotation

The defining characteristic of the hexagonal crystal system is the presence of at least one six-fold axis of rotation.

Related Concepts:

  • What are the defining symmetry requirements for the hexagonal crystal system?: The hexagonal crystal system is characterized by point groups that possess at least one six-fold axis of rotation. This system comprises 7 distinct point groups.
  • What are the seven point groups that constitute the hexagonal crystal system?: The seven point groups within the hexagonal crystal system are: Hexagonal pyramidal (6), Trigonal dipyramidal ($\bar{6}$), Hexagonal dipyramidal (6/m), Hexagonal trapezohedral (622), Dihexagonal pyramidal (6mm), Ditrigonal dipyramidal ($\bar{6}$m2), and Dihexagonal dipyramidal (6/mmm).

How many space groups are associated with the hexagonal crystal system, and where are they assigned?

Answer: 27 space groups, assigned exclusively to the hexagonal lattice

The hexagonal crystal system is associated with 27 space groups, all of which are assigned exclusively to the hexagonal lattice system.

Related Concepts:

  • How many space groups are associated with the hexagonal crystal system, and where are they assigned?: The hexagonal crystal system is associated with 27 space groups. All of these 27 space groups are assigned exclusively to the hexagonal lattice system.

The hexagonal crystal system is characterized by point groups with at least one six-fold axis of rotation.

Answer: True

The defining characteristic of the hexagonal crystal system is the presence of at least one six-fold axis of rotation.

Related Concepts:

  • What are the defining symmetry requirements for the hexagonal crystal system?: The hexagonal crystal system is characterized by point groups that possess at least one six-fold axis of rotation. This system comprises 7 distinct point groups.

The hexagonal crystal system is associated with 27 space groups, all assigned to the hexagonal lattice system.

Answer: True

The hexagonal crystal system is associated with 27 space groups, and all of these are exclusively assigned to the hexagonal lattice system.

Related Concepts:

  • How many space groups are associated with the hexagonal crystal system, and where are they assigned?: The hexagonal crystal system is associated with 27 space groups. All of these 27 space groups are assigned exclusively to the hexagonal lattice system.

Trigonal Crystal System: Symmetry, Systems, and Space Groups

The trigonal crystal system is unique in that its space groups are assigned to more than one lattice system.

Answer: True

The trigonal crystal system is unique because its space groups are assigned to both the rhombohedral and the hexagonal lattice systems, unlike most other crystal systems which are tied to a single lattice system.

Related Concepts:

  • What is unique about the trigonal crystal system in terms of its associated lattice systems?: The trigonal crystal system is unique because its point groups are associated with more than one lattice system. Specifically, its space groups are assigned to both the rhombohedral and the hexagonal lattice systems, unlike other crystal systems which are typically tied to a single lattice system.
  • How many space groups are associated with the trigonal crystal system, and how are they distributed between lattice systems?: The trigonal crystal system is associated with a total of 25 space groups. Of these, 7 space groups are assigned to the rhombohedral lattice system, and 18 space groups are assigned to the hexagonal lattice system.

Alpha-quartz exhibits trigonal symmetry and is classified under the hexagonal lattice system.

Answer: True

Alpha-quartz is a mineral that demonstrates trigonal symmetry but is classified within the broader hexagonal lattice system, illustrating the relationship between symmetry and lattice classification.

Related Concepts:

  • How many Bravais lattices are there in the hexagonal crystal family, and what are they?: The hexagonal crystal family contains two Bravais lattices: the hexagonal lattice and the rhombohedral lattice. These are often identified by their Pearson symbols, 'hP' for the hexagonal lattice and 'hR' for the rhombohedral lattice.

What is the defining symmetry requirement for the trigonal crystal system?

Answer: Presence of at least one three-fold axis of rotation

The trigonal crystal system is defined by point groups that possess at least one three-fold axis of rotation.

Related Concepts:

  • What are the defining symmetry requirements for the trigonal crystal system?: The trigonal crystal system is defined by point groups that possess at least one three-fold axis of rotation. This system includes 5 distinct point groups.
  • What are the five point groups that constitute the trigonal crystal system?: The five point groups within the trigonal crystal system are: Trigonal pyramidal (represented by 3), Rhombohedral (represented by $\bar{3}$), Trigonal trapezohedral (represented by 32), Ditrigonal pyramidal (represented by 3m), and Ditrigonal scalenohedral (represented by $\bar{3}$m).

How many space groups are associated with the trigonal crystal system, and how are they distributed between lattice systems?

Answer: 25 space groups, with 7 assigned to the rhombohedral and 18 to the hexagonal lattice

The trigonal crystal system is associated with a total of 25 space groups; 7 are assigned to the rhombohedral lattice system, and 18 are assigned to the hexagonal lattice system.

Related Concepts:

  • How many space groups are associated with the trigonal crystal system, and how are they distributed between lattice systems?: The trigonal crystal system is associated with a total of 25 space groups. Of these, 7 space groups are assigned to the rhombohedral lattice system, and 18 space groups are assigned to the hexagonal lattice system.

What is unique about the trigonal crystal system concerning its associated lattice systems?

Answer: Its space groups are assigned to both the rhombohedral and hexagonal lattice systems

The trigonal crystal system is unique because its space groups are assigned to both the rhombohedral and the hexagonal lattice systems, unlike most other crystal systems which are tied to a single lattice system.

Related Concepts:

  • What is unique about the trigonal crystal system in terms of its associated lattice systems?: The trigonal crystal system is unique because its point groups are associated with more than one lattice system. Specifically, its space groups are assigned to both the rhombohedral and the hexagonal lattice systems, unlike other crystal systems which are typically tied to a single lattice system.
  • How many space groups are associated with the trigonal crystal system, and how are they distributed between lattice systems?: The trigonal crystal system is associated with a total of 25 space groups. Of these, 7 space groups are assigned to the rhombohedral lattice system, and 18 space groups are assigned to the hexagonal lattice system.

The trigonal crystal system is defined by point groups possessing at least one six-fold axis of rotation.

Answer: False

The trigonal crystal system is defined by point groups possessing at least one three-fold axis of rotation, not a six-fold axis.

Related Concepts:

  • What are the defining symmetry requirements for the trigonal crystal system?: The trigonal crystal system is defined by point groups that possess at least one three-fold axis of rotation. This system includes 5 distinct point groups.

The trigonal crystal system has 25 associated space groups, all assigned to the hexagonal lattice system.

Answer: False

While the trigonal crystal system has 25 associated space groups, only 18 are assigned to the hexagonal lattice system; the remaining 7 are assigned to the rhombohedral lattice system.

Related Concepts:

  • How many space groups are associated with the trigonal crystal system, and how are they distributed between lattice systems?: The trigonal crystal system is associated with a total of 25 space groups. Of these, 7 space groups are assigned to the rhombohedral lattice system, and 18 space groups are assigned to the hexagonal lattice system.

Lattice Descriptions and Unit Cells

The hexagonal description of the rhombohedral lattice is generally preferred for calculations because its coordinate system includes two 90-degree angles, simplifying mathematical operations.

Answer: True

While the rhombohedral axes description better illustrates the inherent 3m symmetry, the hexagonal description is preferred for calculations due to its simpler coordinate system with two right angles.

Related Concepts:

  • Why is the hexagonal description of the rhombohedral lattice often preferred over the rhombohedral axes description?: The hexagonal description is generally preferred for practical calculations because its coordinate system includes two 90-degree angles, simplifying mathematical operations. However, the rhombohedral axes description is sometimes used because it more clearly illustrates the inherent 3m symmetry of the crystal lattice.

The Pearson symbol for the rhombohedral Bravais lattice is not 'hP'.

Answer: True

The Pearson symbol for the rhombohedral Bravais lattice is 'hR', whereas 'hP' denotes the hexagonal Bravais lattice.

Related Concepts:

  • What is the Pearson symbol for the rhombohedral Bravais lattice?: The Pearson symbol for the rhombohedral Bravais lattice is 'hR'.
  • What is the Pearson symbol for the hexagonal Bravais lattice?: The Pearson symbol for the hexagonal Bravais lattice is 'hP'.

The formula V = a²c * sin(60°) is used to calculate the unit cell volume within the hexagonal crystal family.

Answer: True

This formula correctly accounts for the geometry of the hexagonal prism unit cell, where 'a' represents the lengths of the base axes and 'c' is the height.

Related Concepts:

  • What is the formula for calculating the unit cell volume in the hexagonal crystal family?: The volume of a unit cell in the hexagonal crystal family is calculated using the formula V = a²c * sin(60°). This formula accounts for the dimensions of the hexagonal prism unit cell, where 'a' is the length of the base axes and 'c' is the height.
  • What is the characteristic symmetry element of the hexagonal crystal system?: The defining characteristic of the hexagonal crystal system is the presence of at least one six-fold axis of rotation. This symmetry element dictates the overall arrangement of atoms and the resulting crystal shape.

What is the conventional description of a unit cell within the hexagonal crystal family?

Answer: A right rhombic prism

Conventionally, a unit cell in the hexagonal crystal family is described as a right rhombic prism, characterized by two equal axes at 120 degrees and a perpendicular third axis.

Related Concepts:

  • What is the conventional description of a unit cell within the hexagonal crystal family?: Conventionally, a unit cell in the hexagonal crystal family is described as a right rhombic prism. This prism has two equal axes, typically denoted as 'a', which are separated by an angle of 120 degrees (gamma). A third axis, 'c', is perpendicular to the plane containing the 'a' axes and represents the height, which may differ in length from 'a'.

In the hexagonal unit cell description, what is the angle between the two equal 'a' axes?

Answer: 120 degrees

The hexagonal unit cell is defined by two equal axes ('a') that are separated by an angle of 120 degrees.

Related Concepts:

  • What is the conventional description of a unit cell within the hexagonal crystal family?: Conventionally, a unit cell in the hexagonal crystal family is described as a right rhombic prism. This prism has two equal axes, typically denoted as 'a', which are separated by an angle of 120 degrees (gamma). A third axis, 'c', is perpendicular to the plane containing the 'a' axes and represents the height, which may differ in length from 'a'.

When the rhombohedral lattice system is represented using a hexagonal unit cell, what type of centering is used?

Answer: R-centered

When the rhombohedral lattice system is described using a hexagonal unit cell, it is represented by an R-centered cell.

Related Concepts:

  • What are the two settings used to describe the rhombohedral lattice within a hexagonal unit cell?: The rhombohedral lattice can be described using two settings within a hexagonal unit cell: the obverse setting and the reverse setting. These settings differ in the fractional coordinates of the additional lattice points that define the rhombohedral centering.

Why is the hexagonal description of the rhombohedral lattice often preferred over the rhombohedral axes description?

Answer: Its coordinate system includes two 90-degree angles, simplifying math

The hexagonal description is generally preferred for practical calculations because its coordinate system includes two 90-degree angles, simplifying mathematical operations.

Related Concepts:

  • Why is the hexagonal description of the rhombohedral lattice often preferred over the rhombohedral axes description?: The hexagonal description is generally preferred for practical calculations because its coordinate system includes two 90-degree angles, simplifying mathematical operations. However, the rhombohedral axes description is sometimes used because it more clearly illustrates the inherent 3m symmetry of the crystal lattice.

What is the formula for calculating the unit cell volume in the hexagonal crystal family?

Answer: V = a²c * sin(60°)

The volume of a unit cell in the hexagonal crystal family is calculated using the formula V = a²c * sin(60°), accounting for the geometry of the hexagonal prism.

Related Concepts:

  • What is the formula for calculating the unit cell volume in the hexagonal crystal family?: The volume of a unit cell in the hexagonal crystal family is calculated using the formula V = a²c * sin(60°). This formula accounts for the dimensions of the hexagonal prism unit cell, where 'a' is the length of the base axes and 'c' is the height.
  • What is the characteristic symmetry element of the hexagonal crystal system?: The defining characteristic of the hexagonal crystal system is the presence of at least one six-fold axis of rotation. This symmetry element dictates the overall arrangement of atoms and the resulting crystal shape.

What is the Pearson symbol for the rhombohedral Bravais lattice?

Answer: hR

The Pearson symbol for the rhombohedral Bravais lattice is 'hR'.

Related Concepts:

  • What is the Pearson symbol for the rhombohedral Bravais lattice?: The Pearson symbol for the rhombohedral Bravais lattice is 'hR'.
  • What is the Pearson symbol for the hexagonal Bravais lattice?: The Pearson symbol for the hexagonal Bravais lattice is 'hP'.

A unit cell in the hexagonal crystal family is conventionally described as a cube.

Answer: False

A unit cell in the hexagonal crystal family is conventionally described as a right rhombic prism, not a cube.

Related Concepts:

  • What is the conventional description of a unit cell within the hexagonal crystal family?: Conventionally, a unit cell in the hexagonal crystal family is described as a right rhombic prism. This prism has two equal axes, typically denoted as 'a', which are separated by an angle of 120 degrees (gamma). A third axis, 'c', is perpendicular to the plane containing the 'a' axes and represents the height, which may differ in length from 'a'.

Specific Structures: Wurtzite and Nickel Arsenide

The hexagonal close-packed (hcp) structure is classified as a Bravais lattice.

Answer: False

The source states that hcp is not classified as a Bravais lattice because it contains two distinct sets of lattice points.

Related Concepts:

  • What is hexagonal close-packed (hcp) structure?: Hexagonal close-packed (hcp) is a highly dense arrangement of atoms, similar to face-centered cubic (fcc). However, hcp is not classified as a Bravais lattice because it contains two distinct sets of lattice points, rather than just one. It can be constructed from the hexagonal Bravais lattice by adding a two-atom motif to each lattice point.

Lonsdaleite possesses identical atomic positions to the hexagonal close-packed (hcp) structure.

Answer: True

The source material indicates that the atomic positions within the hexagonal close-packed (hcp) structure are identical to those found in lonsdaleite.

Related Concepts:

  • What is the relationship between the hexagonal close-packed (hcp) structure and lonsdaleite?: The atomic positions within the hexagonal close-packed (hcp) structure are identical to those found in lonsdaleite, which is known as the hexagonal form of diamond.

The Wurtzite crystal structure is designated by the Hermann-Mauguin symbol P6_3mc.

Answer: True

The Wurtzite crystal structure is associated with space group No. 186 in the International Union of Crystallography classification, denoted as P6_3mc.

Related Concepts:

  • Describe the Wurtzite crystal structure.: The Wurtzite crystal structure, designated B4 in the Strukturbericht system and hP4 by Pearson symbol, belongs to space group P6_3mc (No. 186). Its symmetry elements include a six-fold screw rotation axis along the c-axis, a mirror plane perpendicular to the {100} direction, and a glide plane parallel to the c-axis with a normal in the {120} direction.
  • What is the specific space group notation for the Wurtzite structure?: The Wurtzite crystal structure is associated with space group No. 186 according to the International Union of Crystallography classification. In the Hermann-Mauguin notation, this space group is designated as P6_3mc.

Wurtzite crystals are non-centrosymmetric.

Answer: True

The source material classifies Wurtzite crystals as non-centrosymmetric, meaning they lack inversion symmetry.

Related Concepts:

  • What are the key properties of Wurtzite crystals related to their symmetry?: Wurtzite crystals are classified as non-centrosymmetric, meaning they lack inversion symmetry. This characteristic symmetry deficiency enables them to exhibit important physical properties such as piezoelectricity and pyroelectricity, which are absent in crystals possessing centrosymmetry.
  • What is the significance of the term 'non-centrosymmetric' for the Wurtzite structure?: The Wurtzite structure is described as non-centrosymmetric because it lacks inversion symmetry. This property is significant as it allows Wurtzite crystals to exhibit phenomena like piezoelectricity and pyroelectricity, which are not possible in crystals with centrosymmetric structures.

In the Wurtzite structure, each atom is tetrahedrally coordinated.

Answer: True

The Wurtzite structure is characterized by tetrahedral coordination, where each atom is surrounded by four nearest neighbors arranged in a tetrahedral geometry.

Related Concepts:

  • How are atoms coordinated in the Wurtzite structure?: In the Wurtzite structure, each atom is tetrahedrally coordinated. This means each atom is surrounded by four nearest neighbors arranged in a tetrahedral geometry, forming the basis of the structure's framework.
  • What is the coordination number and geometry for atoms in the Wurtzite structure?: In the Wurtzite structure, each atom is tetrahedrally coordinated. This means each atom is surrounded by four nearest neighbors arranged in a tetrahedral geometry, forming the basis of the structure's framework.

The Nickel Arsenide structure can be conceptualized as comprising two interpenetrating sublattices: a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice.

Answer: True

This structure is understood as a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice.

Related Concepts:

  • What is the Nickel Arsenide structure?: The Nickel Arsenide structure is formed by two interpenetrating sublattices: a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice. In this arrangement, each nickel atom is octahedrally coordinated by six arsenic atoms, while each arsenic atom is trigonal prismatically coordinated by six nickel atoms.
  • What types of chemical compounds commonly adopt the Nickel Arsenide structure?: Compounds that typically exhibit the Nickel Arsenide structure are generally those formed between transition metals and elements like chalcogens, arsenic, antimony, and bismuth. Examples include transition metal sulfides, selenides, tellurides, arsenides, antimonides, and bismuthides.

In the Nickel Arsenide structure, nickel atoms are octahedrally coordinated by arsenic atoms.

Answer: True

Within the Nickel Arsenide structure, nickel atoms exhibit octahedral coordination, being surrounded by six arsenic atoms.

Related Concepts:

  • What is the Nickel Arsenide structure?: The Nickel Arsenide structure is formed by two interpenetrating sublattices: a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice. In this arrangement, each nickel atom is octahedrally coordinated by six arsenic atoms, while each arsenic atom is trigonal prismatically coordinated by six nickel atoms.
  • What is the coordination number and geometry for atoms in the Nickel Arsenide structure?: In the Nickel Arsenide structure, nickel atoms exhibit octahedral coordination, being surrounded by six arsenic atoms. Arsenic atoms, in turn, display trigonal prismatic coordination, being surrounded by six nickel atoms.

The Wurtzite structure is designated B4 in the Strukturbericht system.

Answer: True

The Wurtzite structure is indeed classified as B4 within the Strukturbericht system, indicating its specific crystallographic notation.

Related Concepts:

  • Describe the Wurtzite crystal structure.: The Wurtzite crystal structure, designated B4 in the Strukturbericht system and hP4 by Pearson symbol, belongs to space group P6_3mc (No. 186). Its symmetry elements include a six-fold screw rotation axis along the c-axis, a mirror plane perpendicular to the {100} direction, and a glide plane parallel to the c-axis with a normal in the {120} direction.

The Nickel Arsenide structure is not understood as a face-centered cubic arrangement of arsenic atoms with nickel atoms in the interstitial sites.

Answer: True

The Nickel Arsenide structure is conceptualized as a hexagonal close-packed arrangement of arsenic atoms, with nickel atoms occupying the octahedral voids, not an FCC arrangement.

Related Concepts:

  • What types of chemical compounds commonly adopt the Nickel Arsenide structure?: Compounds that typically exhibit the Nickel Arsenide structure are generally those formed between transition metals and elements like chalcogens, arsenic, antimony, and bismuth. Examples include transition metal sulfides, selenides, tellurides, arsenides, antimonides, and bismuthides.

The Wurtzite structure exhibits piezoelectricity, contrary to the assertion that it lacks it due to centrosymmetry.

Answer: True

The Wurtzite structure is non-centrosymmetric, which is the prerequisite for exhibiting piezoelectricity and pyroelectricity.

Related Concepts:

  • What are the key properties of Wurtzite crystals related to their symmetry?: Wurtzite crystals are classified as non-centrosymmetric, meaning they lack inversion symmetry. This characteristic symmetry deficiency enables them to exhibit important physical properties such as piezoelectricity and pyroelectricity, which are absent in crystals possessing centrosymmetry.
  • What is the significance of the term 'non-centrosymmetric' for the Wurtzite structure?: The Wurtzite structure is described as non-centrosymmetric because it lacks inversion symmetry. This property is significant as it allows Wurtzite crystals to exhibit phenomena like piezoelectricity and pyroelectricity, which are not possible in crystals with centrosymmetric structures.

Is the hexagonal close-packed (hcp) structure classified as a Bravais lattice?

Answer: No, because it contains two distinct sets of lattice points

The hexagonal close-packed (hcp) structure is not classified as a Bravais lattice because it comprises two distinct sets of lattice points, rather than the single set required for a Bravais lattice.

Related Concepts:

  • What is hexagonal close-packed (hcp) structure?: Hexagonal close-packed (hcp) is a highly dense arrangement of atoms, similar to face-centered cubic (fcc). However, hcp is not classified as a Bravais lattice because it contains two distinct sets of lattice points, rather than just one. It can be constructed from the hexagonal Bravais lattice by adding a two-atom motif to each lattice point.
  • What is the relationship between the hexagonal close-packed (hcp) structure and lonsdaleite?: The atomic positions within the hexagonal close-packed (hcp) structure are identical to those found in lonsdaleite, which is known as the hexagonal form of diamond.

What is the specific space group notation for the Wurtzite crystal structure?

Answer: P6_3mc

The Wurtzite crystal structure is associated with space group No. 186, which is designated as P6_3mc in the Hermann-Mauguin notation.

Related Concepts:

  • Describe the Wurtzite crystal structure.: The Wurtzite crystal structure, designated B4 in the Strukturbericht system and hP4 by Pearson symbol, belongs to space group P6_3mc (No. 186). Its symmetry elements include a six-fold screw rotation axis along the c-axis, a mirror plane perpendicular to the {100} direction, and a glide plane parallel to the c-axis with a normal in the {120} direction.
  • What does the Hermann-Mauguin symbol P6_3mc signify for the Wurtzite structure?: The Hermann-Mauguin symbol P6_3mc for the Wurtzite structure indicates: 'P' for a primitive lattice, '6_3' for a six-fold screw rotation axis along the c-axis, '.m.' for a mirror plane perpendicular to the {100} direction, and '..c' for a glide plane parallel to the c-axis with a normal in the {120} direction.

Which physical properties can Wurtzite crystals exhibit due to their non-centrosymmetric nature?

Answer: Piezoelectricity and pyroelectricity

Wurtzite crystals, being non-centrosymmetric, possess the capability to exhibit piezoelectricity and pyroelectricity.

Related Concepts:

  • What are the key properties of Wurtzite crystals related to their symmetry?: Wurtzite crystals are classified as non-centrosymmetric, meaning they lack inversion symmetry. This characteristic symmetry deficiency enables them to exhibit important physical properties such as piezoelectricity and pyroelectricity, which are absent in crystals possessing centrosymmetry.
  • What is the significance of the term 'non-centrosymmetric' for the Wurtzite structure?: The Wurtzite structure is described as non-centrosymmetric because it lacks inversion symmetry. This property is significant as it allows Wurtzite crystals to exhibit phenomena like piezoelectricity and pyroelectricity, which are not possible in crystals with centrosymmetric structures.

How are atoms coordinated in the Wurtzite structure?

Answer: Tetrahedrally

In the Wurtzite structure, each atom is tetrahedrally coordinated, meaning it is surrounded by four nearest neighbors arranged in a tetrahedral geometry.

Related Concepts:

  • How are atoms coordinated in the Wurtzite structure?: In the Wurtzite structure, each atom is tetrahedrally coordinated. This means each atom is surrounded by four nearest neighbors arranged in a tetrahedral geometry, forming the basis of the structure's framework.
  • What is the coordination number and geometry for atoms in the Wurtzite structure?: In the Wurtzite structure, each atom is tetrahedrally coordinated. This means each atom is surrounded by four nearest neighbors arranged in a tetrahedral geometry, forming the basis of the structure's framework.

In the Nickel Arsenide structure, how are the nickel atoms coordinated?

Answer: Octahedrally

In the Nickel Arsenide structure, nickel atoms are octahedrally coordinated by six arsenic atoms.

Related Concepts:

  • What is the Nickel Arsenide structure?: The Nickel Arsenide structure is formed by two interpenetrating sublattices: a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice. In this arrangement, each nickel atom is octahedrally coordinated by six arsenic atoms, while each arsenic atom is trigonal prismatically coordinated by six nickel atoms.
  • What is the coordination number and geometry for atoms in the Nickel Arsenide structure?: In the Nickel Arsenide structure, nickel atoms exhibit octahedral coordination, being surrounded by six arsenic atoms. Arsenic atoms, in turn, display trigonal prismatic coordination, being surrounded by six nickel atoms.

In the Nickel Arsenide structure, how are the arsenic atoms coordinated?

Answer: Trigonal prismatically

In the Nickel Arsenide structure, arsenic atoms are coordinated trigonal prismatically by six nickel atoms.

Related Concepts:

  • What is the Nickel Arsenide structure?: The Nickel Arsenide structure is formed by two interpenetrating sublattices: a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice. In this arrangement, each nickel atom is octahedrally coordinated by six arsenic atoms, while each arsenic atom is trigonal prismatically coordinated by six nickel atoms.
  • What is the coordination number and geometry for atoms in the Nickel Arsenide structure?: In the Nickel Arsenide structure, nickel atoms exhibit octahedral coordination, being surrounded by six arsenic atoms. Arsenic atoms, in turn, display trigonal prismatic coordination, being surrounded by six nickel atoms.

The Nickel Arsenide structure can be conceptualized as a hexagonal close-packed arrangement of which element, with the other element occupying specific voids?

Answer: Arsenic atoms packed, Nickel in octahedral voids

The Nickel Arsenide structure is understood as a hexagonal close-packed arrangement of arsenic atoms, with nickel atoms occupying the octahedral voids within this packing.

Related Concepts:

  • How can the Nickel Arsenide structure be described in relation to close-packing?: The Nickel Arsenide structure can be understood as a hexagonal close-packed (HCP) arrangement of arsenic atoms, with nickel atoms occupying all the available octahedral voids within this packing.
  • What types of chemical compounds commonly adopt the Nickel Arsenide structure?: Compounds that typically exhibit the Nickel Arsenide structure are generally those formed between transition metals and elements like chalcogens, arsenic, antimony, and bismuth. Examples include transition metal sulfides, selenides, tellurides, arsenides, antimonides, and bismuthides.

Compounds that commonly adopt the Nickel Arsenide structure are typically formed between which classes of elements?

Answer: Transition metals and chalcogens, arsenic, antimony, or bismuth

The Nickel Arsenide structure is characteristic of compounds formed between transition metals and elements such as chalcogens, arsenic, antimony, and bismuth.

Related Concepts:

  • What types of chemical compounds commonly adopt the Nickel Arsenide structure?: Compounds that typically exhibit the Nickel Arsenide structure are generally those formed between transition metals and elements like chalcogens, arsenic, antimony, and bismuth. Examples include transition metal sulfides, selenides, tellurides, arsenides, antimonides, and bismuthides.

How are multi-element structures, such as binary compounds, often conceptualized within the hexagonal crystal family?

Answer: As multiple interpenetrating sublattices

Multi-element structures within the hexagonal crystal family are frequently conceptualized as multiple interpenetrating sublattices.

Related Concepts:

  • What are multi-element structures in the context of the hexagonal crystal family?: Multi-element structures, such as binary compounds, frequently adopt crystal structures based on the hexagonal crystal family. These structures can be conceptualized as multiple interpenetrating sublattices, where each sublattice occupies the interstitial spaces within the others.

What does the Hermann-Mauguin symbol P6_3mc for the Wurtzite structure signify?

Answer: A primitive lattice, a six-fold screw axis, and mirror/glide planes

The symbol P6_3mc indicates a primitive lattice ('P'), a six-fold screw rotation axis along the c-axis ('6_3'), and mirror/glide planes ('.m.' and '..c').

Related Concepts:

  • What does the Hermann-Mauguin symbol P6_3mc signify for the Wurtzite structure?: The Hermann-Mauguin symbol P6_3mc for the Wurtzite structure indicates: 'P' for a primitive lattice, '6_3' for a six-fold screw rotation axis along the c-axis, '.m.' for a mirror plane perpendicular to the {100} direction, and '..c' for a glide plane parallel to the c-axis with a normal in the {120} direction.

Mineral and Compound Examples

Minerals such as dolomite and calcite do not belong to the hexagonal crystal system.

Answer: True

The source lists calcite as an example of the trigonal crystal system, not the hexagonal crystal system.

Related Concepts:

  • Can you provide examples of minerals that belong to the trigonal crystal system?: Yes, several minerals exhibit symmetries of the trigonal crystal system. Examples include carlinite, jarosite, dolomite, ilmenite, alpha-quartz, cinnabar, schorl, cerite, tourmaline, alunite, lithium tantalate, antimony, hematite, corundum, and calcite.

Minerals such as nepheline and beryl are examples of the hexagonal crystal system.

Answer: True

The source material explicitly lists nepheline and beryl as minerals belonging to the hexagonal crystal system.

Related Concepts:

  • Can you provide examples of minerals that belong to the hexagonal crystal system?: Minerals exhibiting the symmetries of the hexagonal crystal system include nepheline, cancrinite, cesanite, apatite, vanadinite, kalsilite, beta-quartz, greenockite, wurtzite, benitoite, and beryl.

Gallium Nitride (GaN) is a notable example of a compound that crystallizes in the Wurtzite structure.

Answer: True

Gallium Nitride (GaN) is frequently cited as a semiconductor compound that adopts the Wurtzite crystal structure.

Related Concepts:

  • What are some common examples of compounds that crystallize in the Wurtzite structure?: Numerous compounds adopt the Wurtzite structure, particularly semiconductors. Notable examples include wurtzite itself (a form of ZnS), silver iodide (AgI), zinc oxide (ZnO), cadmium sulfide (CdS), cadmium selenide (CdSe), silicon carbide ($α$-SiC), gallium nitride (GaN), aluminum nitride (AlN), and boron nitride (w-BN).
  • What is the general characteristic of compounds that adopt the Wurtzite structure?: Many compounds that adopt the Wurtzite structure are semiconductors. Examples include zinc oxide (ZnO), cadmium sulfide (CdS), silicon carbide (SiC), and gallium nitride (GaN), among others.

Which of the following minerals is cited as an example of the trigonal crystal system?

Answer: Calcite

Calcite is explicitly listed as an example of a mineral belonging to the trigonal crystal system.

Related Concepts:

  • Can you provide examples of minerals that belong to the trigonal crystal system?: Yes, several minerals exhibit symmetries of the trigonal crystal system. Examples include carlinite, jarosite, dolomite, ilmenite, alpha-quartz, cinnabar, schorl, cerite, tourmaline, alunite, lithium tantalate, antimony, hematite, corundum, and calcite.

Which of the following minerals is cited as an example of the hexagonal crystal system?

Answer: Apatite

Apatite is listed as a mineral that exhibits the symmetries of the hexagonal crystal system.

Related Concepts:

  • Can you provide examples of minerals that belong to the hexagonal crystal system?: Minerals exhibiting the symmetries of the hexagonal crystal system include nepheline, cancrinite, cesanite, apatite, vanadinite, kalsilite, beta-quartz, greenockite, wurtzite, benitoite, and beryl.

Which of the following is a common example of a compound crystallizing in the Wurtzite structure?

Answer: Gallium Nitride (GaN)

Gallium Nitride (GaN) is frequently cited as a semiconductor compound that adopts the Wurtzite crystal structure.

Related Concepts:

  • What are some common examples of compounds that crystallize in the Wurtzite structure?: Numerous compounds adopt the Wurtzite structure, particularly semiconductors. Notable examples include wurtzite itself (a form of ZnS), silver iodide (AgI), zinc oxide (ZnO), cadmium sulfide (CdS), cadmium selenide (CdSe), silicon carbide ($α$-SiC), gallium nitride (GaN), aluminum nitride (AlN), and boron nitride (w-BN).
  • What is the general characteristic of compounds that adopt the Wurtzite structure?: Many compounds that adopt the Wurtzite structure are semiconductors. Examples include zinc oxide (ZnO), cadmium sulfide (CdS), silicon carbide (SiC), and gallium nitride (GaN), among others.

Which mineral is listed as an example of the hexagonal crystal system?

Answer: Beryl

Beryl is explicitly listed as a mineral belonging to the hexagonal crystal system.

Related Concepts:

  • Can you provide examples of minerals that belong to the hexagonal crystal system?: Minerals exhibiting the symmetries of the hexagonal crystal system include nepheline, cancrinite, cesanite, apatite, vanadinite, kalsilite, beta-quartz, greenockite, wurtzite, benitoite, and beryl.

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