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The Purity Standard

Understanding the precise measure of precious metals, from ancient karats to modern millesimal scales.

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Introduction to Fineness

Defining Fineness

The fineness of a precious metal objectโ€”such as a coin, bar, or piece of jewelryโ€”quantifies the weight of pure precious metal it contains relative to its total weight. This total weight includes any added alloying base metals and trace impurities.

Alloys are intentionally introduced to enhance properties like hardness and durability, essential for items like coins and jewelry. They can also modify colors, reduce overall cost per unit weight, or circumvent the expense associated with achieving extremely high purity levels.

Alloying Examples

For instance, copper is frequently alloyed with silver to create a more robust material suitable for coins and jewelry. Historically, "coin silver" typically comprised 90% silver and 10% copper by mass. Similarly, sterling silver, a common standard, consists of 92.5% silver alloyed with 7.5% other metals, predominantly copper, by mass.

Systems of Measurement

Historically and currently, fineness is expressed through various systems. Two prominent methods remain in widespread use:

  • Millesimal Fineness: Expressed in parts per 1,000.
  • Karats (or Carats): Exclusively used for gold, measuring parts per 24. For example, 18 karat gold signifies an alloy that is 18/24 (or 75%) gold by mass.

Millesimal Fineness

The Parts Per Thousand Standard

Millesimal fineness denotes the purity of precious metal alloysโ€”specifically platinum, gold, and silverโ€”by specifying the number of pure metal parts per 1,000 parts of the total alloy by mass. For example, an alloy composed of 75% pure gold is designated as "750" fineness.

This system is prevalent across many European countries, often marked by decimal stamps (e.g., "585", "750"). It serves as an extension of the older karat system, which uses a 24-part scale (e.g., "18 karat" equates to 750 parts per 1,000).

Typically, millesimal fineness is rounded to a three-figure number, particularly when used for official hallmarks, though the actual purity might slightly deviate from traditional standards.

Platinum Fineness

Purity Levels

Platinum, known for its rarity and density, is often found in high purities. Common millesimal finenesses include:

  • 999.95: Often considered effectively pure; the most common standard for platinum bullion coins and bars.
  • 999 (Three Nines Fine): A widely recognized high purity standard.
  • 950: The most prevalent fineness for platinum jewelry, balancing purity with enhanced durability.
  • 900 (One Nine Fine): Indicates a substantial proportion of pure platinum.
  • 850
  • 750

Gold Fineness

Purity Standards

Gold fineness is measured across a wide spectrum, from near-absolute purity to alloys used in jewelry. Notable standards include:

  • 999.999 (Six Nines Fine): The purest gold ever produced, achieved by the Perth Mint in 1957.
  • 999.99 (Five Nines Fine): The highest purity currently produced, often used by the Royal Canadian Mint for commemorative coins.
  • 999.9 (Four Nines Fine): A popular standard, seen in coins like the Canadian Gold Maple Leaf and American Buffalo.
  • 999 (Three Nines Fine): Also known as 24 karat, used for Chinese Gold Panda coins.
  • 995: The minimum standard for Good Delivery gold bars.
  • 990 (Two Nines Fine)
  • 986: Historically used by Venetian and Holy Roman Empire mints (Ducat fineness).
  • 965: Thai standard, often considered equivalent to 23 karat.
  • 958 (23 Karat)
  • 916 (22 Karat): Known as Crown gold, historically common for bullion coins like British Sovereigns, South African Krugerrands, and modern American Gold Eagles. It's also a standard for jewelry in India.
  • 900 (18 Karat): Used in Latin Monetary Union coinage (e.g., French 20 francs).
  • 834 (20 Karat)
  • 750 (18 Karat): A typical fineness for modern jewelry in Europe. It's also the maximum fineness used for gemstone-set jewelry to ensure metal hardness.
  • 625 (15 Karat)
  • 585 (14 Karat): The most common fineness for jewelry in the United States.
  • 500 (12 Karat)
  • 417 (10 Karat): Historically the minimum standard in the US.
  • 375 (9 Karat): Minimum standard in some Commonwealth realms and parts of Europe.
  • 333 (8 Karat): Minimum standard in Germany since 1884, and also used in several other European countries.

Silver Fineness

Purity Levels

Silver fineness varies significantly, reflecting its use in coinage, bullion, and intricate craftsmanship:

  • 999.99 (Five Nines Fine): The purest silver ever produced, by Royal Silver Company of Bolivia.
  • 999.9 (Four Nines Fine): Used by the Royal Canadian Mint for Silver Maple Leaf coins.
  • 999 (Fine Silver / Three Nines Fine): Standard for Good Delivery bullion bars and most modern silver bullion coins.
  • 980: A standard used in Mexico (circa 1930โ€“1945).
  • 958 (Britannia Silver): A UK standard, representing 11 oz, 10 pennyweights per troy pound.
  • 950: French 1st Standard.
  • 947.9: Russian standard (91 zolotnik).
  • 935: Swiss standard, often used for watchcases and Scandinavian jewelry post-WWII.
  • 925 (Sterling Silver): The UK standard since the 12th century, equivalent to Spanish "plata de primera ley".
  • 917: Used for Indian rupees during the British Raj and some Brazilian coins.
  • 916: Russian standard (88 zolotnik).
  • 900 (One Nine Fine / Coin Silver): Used in historical US silver coins (e.g., Flowing Hair, 1837-1964) and some commemorative issues.
  • 892.4: US "standard silver" defined by the Coinage Act of 1792.
  • 875: Russian standard (84 zolotnik), also used for export watchcases.
  • 868: Imperial Russian coinage (1797-1885).
  • 835: Predominantly used in Germany, the Netherlands, and Latin Monetary Union coins.
  • 833 (5/6 Fine): Common standard in continental Europe, particularly Dutch, Swedish, and German silver.
  • 830: Common standard in older Scandinavian silver.
  • 800: Minimum silver standard in Germany post-1884, French 2nd standard, and Canadian circulating coinage (1920-1966).
  • 750: Uncommon silver standard found in older German, Swiss, and Austro-Hungarian silver.
  • 720 (Decoplata): Used in many Mexican and Dutch coins, as well as some from Portugal, Japan, Uruguay, and Morocco.
  • 600: Used in some Japanese coins (e.g., 100 yen, 1957-1966).
  • 500: Standard for British coinage (1920-1946) and some South American coins.
  • 350: Used for US "war nickels" (1942-1945).

The Karat System

Measuring Gold Purity

The karat (US spelling, symbol k or Kt) or carat (UK spelling, symbol c or Ct) is a fractional system used to denote the purity of gold alloys, representing parts fine per 24 parts of the whole. This system is codified by US federal law.

The formula for calculating karat rating is:

C = 24 * (M_g / M_m)

Where:

  • C is the karat rating.
  • M_g is the mass of pure gold in the alloy.
  • M_m is the total mass of the alloy.

Understanding Karats:

  • 24-karat gold is considered pure gold (though 100% purity is practically unattainable; commerce permits a minimum of 99.95%).
  • 18-karat gold signifies 18 parts gold out of 24 total parts (75% gold).
  • 12-karat gold signifies 12 parts gold out of 24 total parts (50% gold).

Historically, in Britain, karats were further divisible into grains and quarts. The carat system is increasingly supplemented or replaced by the millesimal system, especially for bullion, though it remains dominant for jewelry.

Approximate Conversion to Percentage:

  • 14k: 58.33%โ€“62.50% gold (commonly cited as 58.33%)
  • 18k: 75.00%โ€“79.16% gold (commonly cited as 75.00%)
  • 22k: 91.66%โ€“95.83% gold (commonly cited as 91.66%)
  • 23k: 95.83%โ€“99.95% gold (commonly cited as 95.83%)
  • 24k: 99.95%โ€“100% gold (commonly cited as 99.95%)

Volume vs. Mass: It's important to note that karat ratings are based on mass. Due to density differences (gold is significantly denser than silver or copper), the volume of pure gold in an alloy can be considerably less than its mass percentage suggests. For example, 18k yellow gold (75% gold, 12.5% silver, 12.5% copper by mass) contains only about 60% gold by volume.

Verifying Fineness

Methods and Standards

Accurately verifying the marked fineness of precious metals typically involves two primary methods:

  • Metallurgical Assay: This destructive method involves chemically analyzing a sample of the metal to determine its precise composition.
  • X-ray Fluorescence (XRF): A non-destructive technique that measures the elemental composition of the metal's surface. However, XRF can be misled by thick plating, as it only analyzes the outermost layer.

Legal Purity Standards:

Regulatory bodies set standards to prevent fraud. For instance, in the United States:

  • The actual purity of marked gold articles must not be more than 0.003 below the marked purity (e.g., .996 fine for gold marked .999 fine).
  • The actual purity of marked silver articles must not be more than 0.004 below the marked purity.

These regulations ensure a degree of trust in the stated fineness of precious metal goods.

Understanding Fine Weight

The Weight of Pure Metal

The fine weight refers to the specific weight of the precious metal component within an alloy. For example, 1 troy ounce of 18-karat gold (which is 750 parts per 1,000 fine) has a fine weight of 0.75 troy ounces of pure gold.

Many modern government-issued bullion coins explicitly state their fine weight. For instance, an American Gold Eagle coin designated as "One Oz. Fine Gold" weighs slightly more than 1.091 troy ounces in total to account for the alloy needed for durability.

Traditional Silver Mass Calculation

British Troy System

In Britain, silver fineness was traditionally expressed based on the mass of silver within a troy pound (12 troy ounces). This was measured in troy ounces and pennyweights (1/20th of a troy ounce).

Britannia Silver, for example, has a fineness of 11 ounces and 10 pennyweights per troy pound, equating to approximately 95.833% silver.

Sterling Silver, conversely, has a fineness of 11 ounces and 2 pennyweights per troy pound, precisely 92.5% silver.

These traditional measures highlight the historical methods used to define and communicate silver purity before the widespread adoption of the millesimal system.

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References

References

  1.  U.S. Mint abandons 90 percent silver composition
  2.  Walter W. Skeat (1888), An Etymological Dictionary of the English Language
A full list of references for this article are available at the Fineness Wikipedia page

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Important Notice

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